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Reductive Ring Openings of Carbohydrate Benzylidene Acetals Using Borane-Trimethylamine and Aluminium Chloride. Regioselectivity and Solvent Dependance
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
1983 (English)In: Journal of carbohydrate chemistry, ISSN 0732-8303, E-ISSN 1532-2327, Vol. 2, no 3, 305-311 p.Article in journal (Refereed) Published
Abstract [en]

Regioselective reductive ring openings of 4, 6-O-benzylidene acetals of hexopyranosides are described using borane trimethylamine-aluminium chloride. Using toluene as solvent, 4-O-benzyl ethers with the 6-OH free are obtained. Using tetrahydrofuran as solvent. 6-O-benzyl ethers with the 4-OH free are obtained.

Place, publisher, year, edition, pages
1983. Vol. 2, no 3, 305-311 p.
National Category
Polymer Technologies Polymer Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-80453OAI: oai:DiVA.org:kth-80453DiVA: diva2:498091
Note
NR 20140805Available from: 2012-02-11 Created: 2012-02-09 Last updated: 2017-12-07Bibliographically approved

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