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Molybdenum-Catalyzed and Tungsten-Catalyzed Enantioselective Allylic Substitutions
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-1743-7650
2012 (English)In: Topics in Organometallic Chemistry / [ed] Kazmaier, U, Springer Berlin/Heidelberg, 2012, 209-234 p.Chapter in book (Other academic)
Abstract [en]

Asymmetric allylic substitutions catalyzed by molybdenum and tungsten complexes provide branched chiral products from unsymmetrically substituted allylic reagents. Highly selective chiral ligands are available for both types of reactions, but for the tungsten-catalyzed substitutions, enantioselective reactions are only possible starting from achiral linear allylic substrates. A variety of stabilized carbanions can be used as nucleophiles. The molybdenum-catalyzed reaction has been applied to the synthesis of several biologically active compounds.

Place, publisher, year, edition, pages
Springer Berlin/Heidelberg, 2012. 209-234 p.
, Topics in Organometallic Chemistry, ISSN 1436-6002 ; 38
Keyword [en]
Allylation, Bispyridylamide, Molybdenum, Phosphinooxazoline, Regioselectivity, Tungsten
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-91276DOI: 10.1007/3418_2011_11ISI: 000299173100005ScopusID: 2-s2.0-82055194065ISBN: 978-3-642-22748-6OAI: diva2:508974
QC 20120312Available from: 2012-03-12 Created: 2012-03-12 Last updated: 2012-03-12Bibliographically approved

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