Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
An Air-Stable Fe3S4 Complex with Properties Similar to Those of the HOXair State of the Diiron Hydrogenases
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Applied Electrochemistry.
Show others and affiliations
2012 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, no 27, 4259-4263 p.Article in journal (Refereed) Published
Abstract [en]

A Fe3S4 complex bridged by azapropanedithiolate (adt), complex 6, was prepared as a potential model of the HOXair state of [FeFe]-hydrogenases. Complex 6 was characterized by IR and 1H NMR spectroscopy, and its structure was determined by X-ray crystallography. The electrochemical studies show that complex 6 is redox-active under acidic conditions, which provides insight into the catalytic mechanism. Hydrogen evolution, driven by visible light, was observed in CH3CN/D2O solution by online mass spectroscopy.

Place, publisher, year, edition, pages
2012. no 27, 4259-4263 p.
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-103374DOI: 10.1002/ejic.201200632ISI: 000308590000001Scopus ID: 2-s2.0-84866295322OAI: oai:DiVA.org:kth-103374DiVA: diva2:560847
Funder
Swedish Research CouncilKnut and Alice Wallenberg Foundation
Note

QC 20121016

Available from: 2012-10-16 Created: 2012-10-11 Last updated: 2017-12-07Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Åkermark, Torbjörn
By organisation
Applied Electrochemistry
In the same journal
European Journal of Inorganic Chemistry
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 29 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf