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An Air-Stable Fe3S4 Complex with Properties Similar to Those of the HOXair State of the Diiron Hydrogenases
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Applied Electrochemistry.
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2012 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-0682, no 27, 4259-4263 p.Article in journal (Refereed) Published
Abstract [en]

A Fe3S4 complex bridged by azapropanedithiolate (adt), complex 6, was prepared as a potential model of the HOXair state of [FeFe]-hydrogenases. Complex 6 was characterized by IR and 1H NMR spectroscopy, and its structure was determined by X-ray crystallography. The electrochemical studies show that complex 6 is redox-active under acidic conditions, which provides insight into the catalytic mechanism. Hydrogen evolution, driven by visible light, was observed in CH3CN/D2O solution by online mass spectroscopy.

Place, publisher, year, edition, pages
2012. no 27, 4259-4263 p.
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Chemical Sciences
URN: urn:nbn:se:kth:diva-103374DOI: 10.1002/ejic.201200632ISI: 000308590000001ScopusID: 2-s2.0-84866295322OAI: diva2:560847
Swedish Research CouncilKnut and Alice Wallenberg Foundation

QC 20121016

Available from: 2012-10-16 Created: 2012-10-11 Last updated: 2012-10-16Bibliographically approved

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Åkermark, Torbjörn
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