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Cu K beta(2,5) X-ray emission spectroscopy as a tool for characterization of monovalent copper compounds
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Applied Physical Chemistry.
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2012 (English)In: Journal of Analytical Atomic Spectrometry, ISSN 0267-9477, E-ISSN 1364-5544, Vol. 27, no 11, 1882-1888 p.Article in journal (Refereed) Published
Abstract [en]

Cu Kβ 2,5 X-ray emission and resonant inelastic X-ray scattering measurements were performed on monovalent and divalent copper compounds. The data were compared with the results of local-density- approximation calculations. The methods were found to be efficient tools for studies of Cu 4p states in the valence band and for distinguishing between different monovalent copper compounds. This is of particular importance for the debate concerning copper corrosion in oxygen-free water.

Place, publisher, year, edition, pages
2012. Vol. 27, no 11, 1882-1888 p.
Keyword [en]
Copper corrosion, Electromagnetic wave emission, Emission spectroscopy, X ray scattering, X rays
National Category
Physical Sciences Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-104943DOI: 10.1039/c2ja30095hISI: 000310479900006Scopus ID: 2-s2.0-84867348657OAI: oai:DiVA.org:kth-104943DiVA: diva2:567914
Funder
Swedish Research Council
Note

QC 20121114

Available from: 2012-11-14 Created: 2012-11-14 Last updated: 2017-12-07Bibliographically approved

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