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The redox effect of the [1,2-(NH)(2)C6H4](2-) ligand in the formation of transition metal compounds
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Applied Physical Chemistry.
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2012 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 48, no 92, 11298-11300 p.Article in journal (Refereed) Published
Abstract [en]

Reactions of the [1,2-(NH)(2)C6H4](2-) dianion (LH22-) with Cp2MII (M = V, Mn) lead to complete or partial oxidation of the metals (M), giving the V-III compound [(eta(5)-Cp)(LH2)(2)-VV( LH2)](-)[Li(THF)(4)](+) (1) and (Mn4Mn2III)-Mn-II oxo cage [Mn-6(LH2)(6)(mu(6)-O)(THF)(4)] (2).

Place, publisher, year, edition, pages
2012. Vol. 48, no 92, 11298-11300 p.
Keyword [en]
ligand, transition element
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Chemical Sciences
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URN: urn:nbn:se:kth:diva-106167DOI: 10.1039/c2cc35213cISI: 000310283000005Scopus ID: 2-s2.0-84867973764OAI: oai:DiVA.org:kth-106167DiVA: diva2:573238
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QC 20121130

Available from: 2012-11-30 Created: 2012-11-29 Last updated: 2017-12-07Bibliographically approved

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