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Multielectron-Transfer Templates via Consecutive Two-Electron Transformations: Iron-Sulfur Complexes Relevant to Biological Enzymes
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2012 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 18, no 44, 13968-13973 p.Article in journal (Refereed) Published
Abstract [en]

[FeFe] hydrogenase mimics: Two polynuclear iron-sulfur complexes (1 and 2; see figure) were prepared and structurally characterized. They are potentially effective and stable multielectron-transfer relays for mediating four- and six-electron transformations via a cascade of reversible two-electron redox steps with relatively narrow potential spans.

Place, publisher, year, edition, pages
2012. Vol. 18, no 44, 13968-13973 p.
Keyword [en]
electrochemistry, electron transfer, hydrogenase, iron complexes
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-106141DOI: 10.1002/chem.201201326ISI: 000310473900009ScopusID: 2-s2.0-84867808441OAI: diva2:573367
Swedish Research CouncilKnut and Alice Wallenberg Foundation

QC 20121130

Available from: 2012-11-30 Created: 2012-11-29 Last updated: 2012-11-30Bibliographically approved

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Sun, Licheng
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