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Thermal ageing of electrical conductivity in carbon nanotube/polyaniline composite films
KTH, School of Information and Communication Technology (ICT), Electronic Systems. KTH, School of Information and Communication Technology (ICT), Centres, VinnExcellence Center for Intelligence in Paper and Packaging, iPACK.
KTH, School of Information and Communication Technology (ICT), Electronic Systems. KTH, School of Information and Communication Technology (ICT), Centres, VinnExcellence Center for Intelligence in Paper and Packaging, iPACK.
KTH, School of Information and Communication Technology (ICT), Electronic Systems. KTH, School of Information and Communication Technology (ICT), Centres, VinnExcellence Center for Intelligence in Paper and Packaging, iPACK.
KTH, School of Information and Communication Technology (ICT), Electronic Systems. KTH, School of Information and Communication Technology (ICT), Centres, VinnExcellence Center for Intelligence in Paper and Packaging, iPACK. Department of Engineering Sciences, Uppsala University.
2013 (English)In: Carbon, ISSN 0008-6223, E-ISSN 1873-3891, Vol. 59, 270-277 p.Article in journal (Refereed) Published
Abstract [en]

The influence of carbon nanotubes on the thermal ageing effect of the electrical conductivity of composite thin films is presented. The composite thin films comprise carbon nanotube/polyaniline nanofibers. When subject to thermal treatment, the presence of nanotubes retards the loss of dopants from the polyaniline and enhances the thermal stability in electrical conductivity of the composite thin films. Specifically, an increase in temperature for the conductivity degradation and a significant reduction in the rate of the conductivity degradation of the composite thin films are observed. Upon prolonged heating, the composite thin films exhibit relative large conductivity at high nanotube content, while the polyaniline thin films become insulating.

Place, publisher, year, edition, pages
Pergamon Press, 2013. Vol. 59, 270-277 p.
Keyword [en]
Acid-Doped Polyaniline, Polymer Composites, Degradation, Stability
National Category
Composite Science and Engineering
Identifiers
URN: urn:nbn:se:kth:diva-116712DOI: 10.1016/j.carbon.2013.03.018ISI: 000320489300028Scopus ID: 2-s2.0-84877690600OAI: oai:DiVA.org:kth-116712DiVA: diva2:600468
Funder
VinnovaSwedish Research Council, 2009-8068
Note

QC 20130729. Updated from submitted to published.

Available from: 2013-01-24 Created: 2013-01-24 Last updated: 2017-12-06Bibliographically approved
In thesis
1. Nanofibrillar Materials for Organic and Printable Electronics
Open this publication in new window or tab >>Nanofibrillar Materials for Organic and Printable Electronics
2013 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

In recent years, organic electronics have attracted great attention due to their multiple advantages such as light weight, flexibility, large area fabrication and cost-effective production processes. The recent progress in fabricating organic electronic devices has been achieved with the development of new materials which provide competing functionalities to the electronics devices.  However, as it happens with all type of technologies, organic electronics is not free from challenges. In the latest OE-A Roadmap for organic and printed electronics (2011), the “red brick walls” were identified, and the following three main challenges were pointed out as the potential roadblocks from the material point of view: electrical performance, solution processability (especially formulations in non-toxic solvents) and environmental stability. Currently there is a significant increasing interest in optimizing or developing novel materials to meet those requirements.

 

This thesis presents processing development and study of nanofibrillar materials and deals with the optimization for its applicability for organic electronics. The overall work presented in the thesis is based on three nanofibrillar materials: Polyaniline (PANI), carbon nanotubes (CNTs) and the CNT/PANI composite. First, the solution processability of carbon nanotubes and polyaniline is studied respectively, and through covalent and non-covalent methods, stable aqueous dispersions of these materials are successfully achieved.

 

Second, a composite consisting of multi-walled carbon nanotubes (MWCNTs) and PANI with a core-shell structure is developed and characterized. The investigation of the effects of the loading and type of nanotubes incorporated in the composite material, led to understanding on the fundamental theory underlying the composite morphology. Based on those findings and by carefully optimizing the synthesis procedure, water dispersible MWCNT/PANI nanofibrillar composite is successfully synthesized becoming compatible with solution processable techniques, such as spray coating and potentially with printing technology. With the incorporation of carbon nanotubes, the nanofibrillar composite reaches conductivities 20 times higher than that of the pure polymer. Moreover, the presence of the nanotubes in the composite material decelerates up to 60 times the thermal ageing of its conductivity, making the polymer more robust and suitable for possible manufacturing processes. Furthermore, the composite material still retains the advantageous properties of PANI: electrochromism, tunable conductivities, and sensing capabilities.

 

Third, the stable dispersions of PANI, CNTs and MWCNT/PANI composite were effectively deposited by spray coating technique on several low-cost substrates (PET, PEN, polyimide and papers), and homogeneous, flexible, large-area films were fabricated. Additionally, by spraying the materials on pre-fabricated inkjet printed electrodes, a pH sensor based on the MWCNT/PANI composite and a humidity sensor based on functionalized MWCNTs capable of working at GHz range were demonstrated, which shows that the nanofibrillar materials studied in this thesis work are promising sensor materials for wireless application at ultra-high frequency (UHF) band.

 

Finally, the humidity sensor was integrated into a sensor-box demonstrating a hybrid interconnection platform where printed electronics can be seamlessly integrated with silicon-based electronics. The integration closes the gap between the two technologies, anticipating the adaption of organic electronic technologies.

Place, publisher, year, edition, pages
Stockholm: KTH Royal Institute of Technology, 2013. xiv, 87 p.
Series
Trita-ICT-ECS AVH, ISSN 1653-6363 ; 12:09
Keyword
Organic electronics, polyaniline, carbon nanotubes, composite, spray coating, solution processability, morphology, electrical conductivity, ageing, sensor, system integration
National Category
Composite Science and Engineering
Identifiers
urn:nbn:se:kth:diva-116714 (URN)978-91-7501-615-3 (ISBN)
Public defence
2013-02-18, Sal D, Forum, KTH-ICT, Isafjordsgatan 39, Kista, 14:00 (English)
Opponent
Supervisors
Note

QC 20130125

Available from: 2013-01-25 Created: 2013-01-24 Last updated: 2013-01-25Bibliographically approved

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