Ionically interacting nanoclay and nanofibrillated cellulose lead to tough bulk nanocomposites in compression by forced self-assembly
2013 (English)In: Journal of Materials Chemistry B, ISSN 2050-750X, Vol. 1, no 6, 835-840 p.Article in journal (Refereed) Published
Several approaches have recently been shown for self-assembled biomimetic composite films, aiming at combinations of high toughness, strength, and stiffness. However, it remains challenging to achieve high toughness using simple processes especially for bulk materials. We demonstrate that ionically interacting cationic native nanofibrillated cellulose (C-NFC) and anionic nanoclay, i.e. montmorillonite (MTM), allow local self-assemblies by a simple centrifugation process to achieve 3D bulk materials. The composite with MTM/C-NFC of 63/37 w/w has a high compressive strain to failure of 37% with distinct plastic deformation behaviour, a high work to fracture of 23.1 MJ m(-3), and a relatively high compression strength of 76 MPa. Unlike the conventionally used sequential deposition methods to achieve well-defined layers for the oppositely charged units as limited to films, the present one-step method allows quick formation of bulk materials and leads to local self-assemblies, however, having a considerable amount of nanovoids and defects between them. We suggest that the nanovoids and defects promote the plastic deformation and toughness. Considering the simple preparation method and bio-based origin of NFC, we expect that the present tough bulk nanocomposites in compression have potential in applications for sustainable and environmentally friendly materials in construction and transportation.
Place, publisher, year, edition, pages
2013. Vol. 1, no 6, 835-840 p.
Layered Silicate Nanocomposites, Microfibrillated Cellulose, Biomimetic Nanocomposites, Polymer Nanocomposites, Native Cellulose, Composites, Bone, Nanofibers, Nacre, Deformation
IdentifiersURN: urn:nbn:se:kth:diva-119487DOI: 10.1039/c2tb00370hISI: 000314800000014ScopusID: 2-s2.0-84876580491OAI: oai:DiVA.org:kth-119487DiVA: diva2:611094
FunderEU, European Research CouncilEU, FP7, Seventh Framework Programme
QC 201303142013-03-142013-03-142013-11-06Bibliographically approved