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Promoting the Activity of Catalysts for the Oxidation of Water with Bridged Dinuclear Ruthenium Complexes
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2013 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 52, no 12, 3398-3401 p.Article in journal (Refereed) Published
Abstract [en]

Solar fuels: Dinuclear ruthenium catalysts prepared from two covalently bridged monomeric catalytic units show outstanding activities towards the oxidation of water with high turnover numbers up to 43 000 and turnover frequencies up to 40 s-1 (see picture). Direct comparison of the performance parameters indicates that the dimers are significantly more active as catalysts than the monomers.

Place, publisher, year, edition, pages
2013. Vol. 52, no 12, 3398-3401 p.
Keyword [en]
artificial photosynthesis, binuclear catalyst, homogeneous catalysis, solar fuels, water splitting
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-121140DOI: 10.1002/anie.201209045ISI: 000316342900016ScopusID: 2-s2.0-84875192385OAI: diva2:616866
Knut and Alice Wallenberg Foundation

QC 20130419

Available from: 2013-04-19 Created: 2013-04-19 Last updated: 2013-04-19Bibliographically approved

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Sun, Licheng
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