Nanocomposite Materials for New Energy Conversion Device
Independent thesis Advanced level (degree of Master (Two Years)), 20 credits / 30 HE creditsStudent thesis
This thesis gives an approach how to develop newperovskite and nanocomposite cathode material for low temperature solid oxidefuel cells on the basis of nanocomposite approach to lower the operatingtemperature of SOFC. BaxCa1-xCoyFe1-yO3-δ(BCCF) and BSCF perovskite or nanocomposite oxides have been synthesized andinvestigated as catalytically potential cathode materials for low temperaturesolid oxide fuel cells (LTSOFC). Some single component materials have been alsosynthesized for new energy conversion device or EFFC. These nanocomposite andperovskite electrical conductors were synthesized by wet chemical, sol gel,co-precipitation and solid state reaction methods. Comparison with that ofcommercial Ba0.5Sr0.5Co0.8Fe0.2O3-δ(BSCF) cathode material, BCCF and locally prepared BSCF exhibit higher electricalconductivities as compared to that of commercial BSCF at same setup andconditions. In particular, novel Ba0.3Ca0.7Co0.8Fe0.2O3-δhas shown the maximum conductivity of 143 S/cm in air and local BSCF withconductivity of 313 S/cm in air at 550°C were measured by DC 4 probe method. Anadditional positive aspect of BCCF is that it is cost effective and works atroom temperature but with small output which will lead SOFC to operate atextremely low temperatures. XRD patterns of the samples reveal perovskite andnanocomposite structures of the said materials. Microstructure studies give thehomogeneous structure and morphology of the nanoparticles by using HighResolution Scanning Electron Microscopy (SEM). Cell resistance has beendetermined by Electrochemical Impedance Spectroscopy (EIS). Devised materialshave shown very good mechanical strength and stability proving their importancein advanced fuel cell technology. Power density of devices from 126 to 192 mWcm-2hasbeen achieved.
Place, publisher, year, edition, pages
2013. , 39 p.
SOFC, New energy conversion device, Nanocomposite & Perovskite materials, BSCF, BCCF, XRD, DC 4 Probe, SEM, EIS
Natural Sciences Engineering and Technology
IdentifiersURN: urn:nbn:se:kth:diva-122675OAI: oai:DiVA.org:kth-122675DiVA: diva2:623227
2013-04-19, Sefstrom room, ITM/Materials Science and Engineering, KTH, Stockholm, 11:00 (English)
Raza, Rizwan, Doctor
Persson, Clas, Associate ProfessorZhu, Bin, Docent