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Regio- and Stereoselective Hydrosilylation of 1,3-Enynes Catalyzed by Palladium
KTH, School of Chemical Science and Engineering (CHE), Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-1743-7650
2013 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 15, no 7, 1444-1447 p.Article in journal (Refereed) Published
Abstract [en]

In the presence of Pd(0) and a phosphine, hydrosilylation of 1,3-enynes with Me2SiHCI proceeds to yield dienylsilanes with the silicon function added to the internal alkyne carbon atom and with (E)-configuration of newly formed olefinic bond. The silanols isolated after hydrolysis of the primarily obtained products serve as precursors to conjugated dienes with different substitution patterns.

Place, publisher, year, edition, pages
2013. Vol. 15, no 7, 1444-1447 p.
Keyword [en]
Cross-Coupling Reactions, Silicon, Alkynes, Hydrides, Lactimidomycin, 1, 3-Dienes, Precursors, Oxidation, Efficient, Silanols
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-123632DOI: 10.1021/ol4001334ISI: 000317327900007ScopusID: 2-s2.0-84875927670OAI: diva2:630223
Swedish Research Council

QC 20130618

Available from: 2013-06-18 Created: 2013-06-13 Last updated: 2013-06-18Bibliographically approved

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