Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Regio- and Stereoselective Hydrosilylation of 1,3-Enynes Catalyzed by Palladium
KTH, School of Chemical Science and Engineering (CHE), Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-1743-7650
2013 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 15, no 7, 1444-1447 p.Article in journal (Refereed) Published
Abstract [en]

In the presence of Pd(0) and a phosphine, hydrosilylation of 1,3-enynes with Me2SiHCI proceeds to yield dienylsilanes with the silicon function added to the internal alkyne carbon atom and with (E)-configuration of newly formed olefinic bond. The silanols isolated after hydrolysis of the primarily obtained products serve as precursors to conjugated dienes with different substitution patterns.

Place, publisher, year, edition, pages
2013. Vol. 15, no 7, 1444-1447 p.
Keyword [en]
Cross-Coupling Reactions, Silicon, Alkynes, Hydrides, Lactimidomycin, 1, 3-Dienes, Precursors, Oxidation, Efficient, Silanols
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-123632DOI: 10.1021/ol4001334ISI: 000317327900007Scopus ID: 2-s2.0-84875927670OAI: oai:DiVA.org:kth-123632DiVA: diva2:630223
Funder
Swedish Research Council
Note

QC 20130618

Available from: 2013-06-18 Created: 2013-06-13 Last updated: 2017-05-30Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Authority records BETA

Moberg, Christina

Search in DiVA

By author/editor
Zhou, HuiMoberg, Christina
By organisation
ChemistryOrganic Chemistry
In the same journal
Organic Letters
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 50 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf