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Deoxyguanosine Phosphate Mediated Sacrificial Bonds Promote Synergistic Mechanical Properties in Nacre-Mimetic Nanocomposites
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology. KTH, School of Chemical Science and Engineering (CHE), Centres, Wallenberg Wood Science Center.ORCID iD: 0000-0001-5818-2378
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2013 (English)In: Biomacromolecules, ISSN 1525-7797, E-ISSN 1526-4602, Vol. 14, no 8, 2531-2535 p.Article in journal (Refereed) Published
Abstract [en]

We show that functionalizing polymer-coated colloidal nanoplatelets with guanosine groups allows synergistic increase of mechanical properties in nacre-mimetic lamellar self-assemblies. Anionic montmorillonite (MTM) was first coated using cationic poly(diallyldimethylammonium chloride) (PDADMAC) to prepare core-shell colloidal platelets, and subsequently the remaining chloride counterions allowed exchange to functional anionic 2'-deoxyguanosine 5'-monophosphate (dGMP) counterions, containing hydrogen bonding donors and acceptors. The compositions were studied using elemental analysis, scanning and transmission electron microscopy, wide-angle X-ray scattering, and tensile testing. The lamellar spacing between the clays increases from 1.85 to 2.14 nm upon addition of the dGMP. Adding dGMP increases the elastic modulus, tensile strength, and strain 33.0%, 40.9%, and 5.6%, respectively, to 13.5 GPa, 67 MPa, and 1.24%, at 50% relative humidity. This leads to an improved toughness seen as a ca. 50% increase of the work-to-failure. This is noteworthy, as previously it has been observed that connecting the core-shell nanoclay platelets covalently or ionically leads to increase of the stiffness but to reduced strain. We suggest that the dynamic supramolecular bonds allow slippage and sacrificial bonds between the self-assembling nanoplatelets, thus promoting toughness, still providing dynamic interactions between the platelets.

Place, publisher, year, edition, pages
2013. Vol. 14, no 8, 2531-2535 p.
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Biochemistry and Molecular Biology
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URN: urn:nbn:se:kth:diva-128480DOI: 10.1021/bm400056cISI: 000323143700011Scopus ID: 2-s2.0-84881566987OAI: oai:DiVA.org:kth-128480DiVA: diva2:647883
Funder
EU, European Research Council
Note

QC 20130912

Available from: 2013-09-12 Created: 2013-09-12 Last updated: 2017-12-06Bibliographically approved

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Berglund, Lars

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