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Electrocatalytic hydrogen evolution from neutral water by molecular cobalt tripyridine-diamine complexes
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2013 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 49, no 82, 9455-9457 p.Article in journal (Refereed) Published
Abstract [en]

A cobalt complex with a tripyridine-diamine pentadentate ligand was found to be a highly active catalyst for electrochemical H-2 production from neutral water, with an activity of 860 mol H-2 (mol cat)(-1) h(-1) (cm(2) Hg)(-1) over 60 h CPE experiment at-1.25 V in a pH 7 phosphate buffer solution, without considerable deactivation.

Place, publisher, year, edition, pages
2013. Vol. 49, no 82, 9455-9457 p.
Keyword [en]
Molybdenum-Oxo Catalyst, Functional Models, Recent Progress, Reduction, Generation, Protons, Cobaloximes, Media
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URN: urn:nbn:se:kth:diva-133979DOI: 10.1039/c3cc43491eISI: 000324758000026ScopusID: 2-s2.0-84883382752OAI: diva2:664223

QC 20131114

Available from: 2013-11-14 Created: 2013-11-14 Last updated: 2013-11-14Bibliographically approved

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Sun, Licheng
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Organic ChemistryCentre of Molecular Devices, CMD
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