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Structure stability of metal-organic framework MIL-53 (Al) in aqueous solutions
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2013 (English)In: International journal of hydrogen energy, ISSN 0360-3199, Vol. 38, no 36, 16710-16715 p.Article in journal (Refereed) Published
Abstract [en]

The structural stability of MIL-53 (Al) in different pH aqueous solutions from room temperature to 100 degrees C has been investigated. Experimental results show MIL-53 (Al) is stable and highly resistant to hydrolysis in neutral and acidic solutions. It can retain its crystallinity and permanent porosity without structural collapse. The good structure stability of MIL-53 (Al) to aqueous solutions is quite unusual among the MOFs. The nitrogen adsorption for the soaked frameworks show a typical type I isotherm. In basic aqueous solution, MIL-53 (Al) undergoes structure transformation.

Place, publisher, year, edition, pages
2013. Vol. 38, no 36, 16710-16715 p.
Keyword [en]
Metal-organic frameworks, Structure stability, Aqueous solution, MIL-53 (Al)
National Category
Energy Engineering
URN: urn:nbn:se:kth:diva-139275DOI: 10.1016/j.ijhydene.2013.07.054ISI: 000327904500095ScopusID: 2-s2.0-84887999389OAI: diva2:685157

QC 20140109

Available from: 2014-01-09 Created: 2014-01-08 Last updated: 2014-01-09Bibliographically approved

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Zhu, Bin
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