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Synthesis, structure, and magnetic properties of some layered compounds based on long-chain sulfonium cations and complex cobalt and copper anions
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Applied Physical Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Applied Physical Chemistry.
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Engineering Material Physics.ORCID iD: 0000-0003-4889-4210
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Applied Physical Chemistry.
2013 (English)In: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 639, no 14, 2613-2617 p.Article in journal (Refereed) Published
Abstract [en]

Two new materials of the composition ({CH3(CH2) 15(CH3)2S}+)2[CoBr 4]2- (1) and ({CH3(CH2) 15(CH3)2S}+)2[CuBr 4]2- (2 and 3), of which the latter exists in two polymorphs, were synthesized. The materials display the synthetically targeted structures, comprising of layers of complex metal ions and layers of long-chain sulfonium cations. The crystal structures of the materials were determined. The interlayer distances are around 24 Å, with metal-metal distances about 8 Å. The magnetic properties of 1 were investigated, and the material is paramagnetic. ({CH3(CH2)15(CH3) 2S}+)2[CuBr4]2 is polymorphic. Both polymorphs crystallize with triclinic symmetry.

Place, publisher, year, edition, pages
2013. Vol. 639, no 14, 2613-2617 p.
Keyword [en]
Cobalt, Copper, Crystal engineering, Layered compounds, Self-assembly, Sulfonium
National Category
Materials Engineering Materials Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-139978DOI: 10.1002/zaac.201300212ISI: 000329497900040Scopus ID: 2-s2.0-84887310051OAI: oai:DiVA.org:kth-139978DiVA: diva2:689648
Note

QC 20140121

Available from: 2014-01-21 Created: 2014-01-16 Last updated: 2017-12-06Bibliographically approved

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Belova, Liubov

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