Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Preparation and electrochemical properties of spinel LiFexCuyMn1.2O4 by ultrasonic spray pyrolysis
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Applied Electrochemistry.ORCID iD: 0000-0001-9203-9313
2014 (English)In: Ceramics International, ISSN 0272-8842, E-ISSN 1873-3956, Vol. 40, no 1, 1019-1027 p.Article in journal (Refereed) Published
Abstract [en]

Nanocrystalline LiFexCuyMn1.2O4 (x and y=0.2, 0.4 and 0.6) particles were prepared by the ultrasonic spray pyrolysis method using nitrate salts at 800 degrees C in air atmosphere. Particle properties were characterized by X-ray diffraction, scanning electron microscopy, and energy dispersive spectroscopy. Also, cyclic voltammetry and galvanostatic tests were performed to investigate the effects of the double substituent and doping amounts on electrochemical behavior. Results show that the aggregation of nanocrystallites around 90 nm size formed submicron spherical cathode particles. Transition metal ratios in particles exhibited a perfect fit with desired amounts. Although the change of iron and copper amounts do not show significant differences in the particle size and shape morphology, they modify the 4 V and 3 V potential plateaus of spinel LiMn2O4. The discharge capacities of LiFe0.2Cu0.6Mn1.2O4 particles are 39 and 23 mAh g(-1) for 4 and 2.6 V potential regions, respectively. 4 V discharge capacity disappeared with increasing of iron and decreasing of copper contents due to random occupation of iron and copper ions in the spinel lattice.

Place, publisher, year, edition, pages
2014. Vol. 40, no 1, 1019-1027 p.
Keyword [en]
Nanostructures, Cathode particles, Spinel structure, Li-ion batteries, Ultrasonic spray pyrolysis
National Category
Ceramics
Identifiers
URN: urn:nbn:se:kth:diva-142510DOI: 10.1016/j.ceramint.2013.06.099ISI: 000330820500130Scopus ID: 2-s2.0-84887619547OAI: oai:DiVA.org:kth-142510DiVA: diva2:703498
Note

QC 20140307

Available from: 2014-03-07 Created: 2014-03-06 Last updated: 2017-12-05Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Authority records BETA

Lindbergh, Göran

Search in DiVA

By author/editor
Lindbergh, Göran
By organisation
Applied Electrochemistry
In the same journal
Ceramics International
Ceramics

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 57 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf