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The application of reversible covalent bonds in catalysis
KTH, School of Chemical Science and Engineering (CHE).
2014 (English)Independent thesis Advanced level (professional degree), 20 credits / 30 HE creditsStudent thesis
Abstract [en]

This work has been concerned with the study of ligand exchange of trimethylborate and its  ability to induce temporary intramolecularity. Experiments aimed at understanding the affinity of various alcohols and amines to boron centers by studying the formation of mixed borate species during equilibrium. Furthermore, a variety of reactions has been screened with the aim to perform catalysis by induced intramolecularity through the trimethylborate.

Abstract [sv]

I detta projekt har ligandutbyte på trimetylborat, samt dess möjlighet att inducera intramolekularitet studerats. Experiment har utförts som inriktats på en fördjupad förståelse för boraffiniteten hos alkoholer och aminer, samt jämvikterna i dessa system. Vidare har reaktioner screenats i sökandet efter en reaktion som kan katalyseras av inducerad intramolelcularitet av trimetylborat.

Place, publisher, year, edition, pages
2014.
Keyword [en]
Induced intramolecularity, tethering, trimethylborate, catalysis, NMR-study
National Category
Organic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-145952OAI: oai:DiVA.org:kth-145952DiVA: diva2:721108
Available from: 2014-06-03 Created: 2014-06-03 Last updated: 2014-06-03Bibliographically approved

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