Spin-orbit interaction mediated molecular dissociation
2014 (English)In: Journal of Chemical Physics, ISSN 0021-9606, E-ISSN 1089-7690, Vol. 140, no 18, 184304- p.Article in journal (Refereed) Published
The effect of the spin-orbit interaction to photofragmentation is investigated in the mercury(II) bromide (HgBr2) molecule. Changes in the fragmentation between the two spin-orbit components of Hg 5d photoionization, as well as within the molecular-field-splitted levels of these components are observed. Dissociation subsequent to photoionization is studied with synchrotron radiation and photoelectron-photoion coincidence spectroscopy. The experimental results are accompanied by relativistic ab initio analysis of the photoelectron spectrum.
Place, publisher, year, edition, pages
2014. Vol. 140, no 18, 184304- p.
IdentifiersURN: urn:nbn:se:kth:diva-147743DOI: 10.1063/1.4873718ISI: 000336782700068ScopusID: 2-s2.0-84904799578OAI: oai:DiVA.org:kth-147743DiVA: diva2:732584
QC 201407042014-07-042014-07-032014-07-04Bibliographically approved