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The influence of a S-to-S bridge in diiron dithiolate models on the oxidation reaction: a mimic of the H-ox(air) state of [FeFe]-hydrogenases
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2014 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 50, no 66, 9255-9258 p.Article in journal (Refereed) Published
Abstract [en]

Two-electron oxidation of a diiron complex (1) containing a bulky S-to-S bridge with an exocyclic carbonyl group affords [1(OH)](+), which replicates the coordination structure and electronic configuration of H-ox(air), and the chemically reversible reaction between 1 and [1(OH)](+) mimics the bioprocess of interconversion of the inactive H-ox(air) and the active H-red states of the [FeFe]-hydrogenases.

Place, publisher, year, edition, pages
2014. Vol. 50, no 66, 9255-9258 p.
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Chemical Sciences
URN: urn:nbn:se:kth:diva-150917DOI: 10.1039/c4cc03583fISI: 000340353300003ScopusID: 2-s2.0-84904766631OAI: diva2:746445
Swedish Energy AgencyKnut and Alice Wallenberg Foundation

QC 20140912

Available from: 2014-09-12 Created: 2014-09-11 Last updated: 2014-09-12Bibliographically approved

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