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Self-assembly of a heteropolyoxopalladate nanocube: [PdII 13AsV 8O34(OH)6] 8-
KTH, School of Engineering Sciences (SCI), Applied Physics, Biomedical and X-ray Physics. Jacobs Univ, Sch Sci & Engn, Germany.
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2008 (English)In: Angewandte Chemie International Edition, ISSN 1433-7851, E-ISSN 1521-3773, Vol. 47, no 49, 9542-9546 p.Article in journal (Refereed) Published
Abstract [en]

(Chemical Equation Presented) Not like the others: A molecular palladium oxide cluster was formed by self-assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II 13AsV 8O34(OH) 6]8- has a distorted cubic shape and edge lengths of about 1 nm. The thirteen PdII ions retain four-coordinate square-planar geometry, in marked contrast to all other known discrete polyoxometalates.

Place, publisher, year, edition, pages
2008. Vol. 47, no 49, 9542-9546 p.
Keyword [en]
Electrochemistry, Nanoclusters, Oxidation catalysis, Palladium, Polyoxometalates, Arsenic, Chemical reactions, Palladium compounds, Self assembly, Vanadium compounds, Chemical equations, Cubic shapes, Edge lengths, Mild reaction conditions, Palladium oxides, Planar geometries, arsenic acid derivative, nanoparticle, palladium oxide, tungsten derivative, tungstoarsenate, article, chemistry, conformation, particle size, Arsenates, Molecular Conformation, Nanoparticles, Tungsten Compounds
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URN: urn:nbn:se:kth:diva-154290DOI: 10.1002/anie.200803527ISI: 000261484200035Scopus ID: 2-s2.0-56749109702OAI: oai:DiVA.org:kth-154290DiVA: diva2:758658
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QC 20141028

Available from: 2014-10-28 Created: 2014-10-17 Last updated: 2017-12-05Bibliographically approved

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