Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Photocatalytic Water Oxidation by Molecular Assemblies Based on Cobalt Catalysts
Show others and affiliations
2014 (English)In: ChemSusChem, ISSN 1864-5631, E-ISSN 1864-564X, Vol. 7, no 9, 2453-2456 p.Article in journal (Refereed) Published
Abstract [en]

Chromophore-catalyst molecular assemblies towards visible light-driven water oxidation were synthesized by covalent integration of a light-harvesting complex [Ru(bpy)(3)](2+) (bpy= 2,2'-bipyridine) and a Co4O4 cubane water oxidation catalyst. The two components were assembled either in linear or macrocyclic configurations. In the presence of the sacrificial reagent, the Ru-Co metallocycle exhibits remarkable photocatalytic activity for oxygen evolution, which is one order of magnitude higher than that of a multicomponent system and exceeds that of a linear assembly by a factor of five, offering access to highly active photocatalyst through molecular design.

Place, publisher, year, edition, pages
2014. Vol. 7, no 9, 2453-2456 p.
Keyword [en]
cobalt, cubanes, homogeneous catalysis, photocatalysis, water splitting
National Category
Other Chemistry Topics
Identifiers
URN: urn:nbn:se:kth:diva-155480DOI: 10.1002/cssc.201402195ISI: 000342813300012Scopus ID: 2-s2.0-85007200968OAI: oai:DiVA.org:kth-155480DiVA: diva2:762500
Funder
Swedish Energy AgencyKnut and Alice Wallenberg Foundation
Note

QC 20141112

Available from: 2014-11-12 Created: 2014-11-06 Last updated: 2017-12-05Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Authority records BETA

Sun, Licheng

Search in DiVA

By author/editor
Sun, Licheng
By organisation
Organic Chemistry
In the same journal
ChemSusChem
Other Chemistry Topics

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 76 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf