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Dissociative recombination of CD3OD2 +
KTH, School of Engineering Sciences (SCI), Physics.
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2005 (English)In: Proceedings of the International Astronomical Union, ISSN 1743-9213, E-ISSN 1743-9221, Vol. 1, 117-124 p.Article in journal (Refereed) Published
Abstract [en]

The branching ratios of the different reaction pathways and the overall rate of the dissociative recombination of CD3OD2 + were measured at the CRYRING storage ring located at the Manne Siegbahn Laboratory in Stockholm, Sweden. A preliminary analysis of the data yielded that formation of methanol accounts for only 6±2% of the total reaction rate. Largely, dissociative recombination of CD3OD 2 + involves fragmentation of the C-O bond, the major process being the three-body break-up forming CD3, OD and D (branching ratio 0.59). A non-negligible formation of interstellar methanol by the previously proposed mechanism is therefore very unlikely.

Place, publisher, year, edition, pages
2005. Vol. 1, 117-124 p.
Keyword [en]
ISM, Laboratory molecular processes, Molecules methods
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-156289DOI: 10.1017/S1743921306007101Scopus ID: 2-s2.0-63549098606OAI: oai:DiVA.org:kth-156289DiVA: diva2:766945
Note

QC 20141128

Available from: 2014-11-28 Created: 2014-11-26 Last updated: 2017-12-05Bibliographically approved

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