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Femtosecond photo-induced dissociation of the trihalide anions I 3 - and I2Br- in solution
KTH, Superseded Departments, Physics.
KTH, Superseded Departments, Physics.
2004 (English)In: ULTRAFAST PHENOMENA XIV, 2004, 499-501 p.Conference paper, Published paper (Refereed)
Abstract [en]

The photo-induced dissociation of the trihalide anions I3 - and I2Br- in methanol and acetonitrile solution is investigated using magic angle and polarization sensitive femtosecond transient absorption spectroscopy. The dissociation of I 2Br- and I3 - in acetonitrile are found to be very similar, except at the earliest times. A noticeable solvent dependence for the dissociation process is seen, e.g. in the degree of vibrational coherence and the rotational temperature of the I2 - fragment and in the amount of recombination.

Place, publisher, year, edition, pages
2004. 499-501 p.
Series
Springer Series in Chemical Physics, ISSN 0172-6218 ; 79
Keyword [en]
acetonitrile, anion, bromine derivative, halide, methanol, solvent, absorption spectroscopy, conference paper, dissociation, photochemistry, rotation, solution and solubility, temperature, vibration
National Category
Physical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-157269ISI: 000228159300152Scopus ID: 2-s2.0-20944450578ISBN: 3-540-24110-8 (print)OAI: oai:DiVA.org:kth-157269DiVA: diva2:771164
Conference
14th International Conference on Ultrafast Phenomena, Niigata, JAPAN, JUL 25-30, 2004
Note

QC 21041212

Available from: 2014-12-12 Created: 2014-12-08 Last updated: 2016-12-16Bibliographically approved

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