Hydrothermal ageing of polylactide/sisal biocomposites. Studies of water absorption behaviour and Physico-Chemical performance
2014 (English)In: Polymer degradation and stability, ISSN 0141-3910, E-ISSN 1873-2321, Vol. 108, 212-222 p.Article in journal (Refereed) Published
An accelerated hydrothermal degrading test was designed in order to analyse the synergic effect of water and temperature on PLA/sisal biocomposites with and without coupling agent. As well, the physicochemical properties of biocomposites were monitored along the hydrothermal test by means of Scanning Electron Microscopy, Size Exclusion Chromatography and Differential Scanning Calorimetry. The addition of fibre induced higher water absorption capability and promoted physical degradation, as observed in the surface topography. During the processing of biocomposites and throughout the hydrothermal ageing, a reduction of molecular weight due to chain scission was found. As a consequence, a faster formation of crystalline domains in the PIA matrix occurred the higher the amount of fibre was, which acted as a nucleating agent. Higher crystallinity was considered as a barrier against the advance of penetrant and a reduction in the diffusion coefficient was shown. The addition of coupling agent presented a different influence depending on the composition, showing an inflection point around 20% of sisal fibre.
Place, publisher, year, edition, pages
2014. Vol. 108, 212-222 p.
Biocomposites, Polylactide (PLA), Natural fibres, Sisal, Hydrothermal degradation, Water absorption
IdentifiersURN: urn:nbn:se:kth:diva-156127DOI: 10.1016/j.polymdegradstab.2014.06.010ISI: 000343380800026ScopusID: 2-s2.0-84903221897OAI: oai:DiVA.org:kth-156127DiVA: diva2:772511
QC 201412172014-12-172014-11-212014-12-17Bibliographically approved