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Investigation of Pt, Ti, TiN and Nano-porous Carbon Electrodes for Implantable Cardioverter-Defibrillator Applications
KTH, Superseded Departments, Materials Science and Engineering.
KTH, Superseded Departments, Materials Science and Engineering.ORCID iD: 0000-0002-4431-0671
KTH, Superseded Departments, Materials Science and Engineering.ORCID iD: 0000-0002-9453-1333
2004 (English)In: Electrochimica Acta, ISSN 0013-4686, E-ISSN 0019-4686, Vol. 49, no 22-23, 4011-4020 p.Article in journal (Refereed) Published
Abstract [en]

 The electrochemical behavior and stability of Pt, Ti, TiN, and nano-porous carbon for implantable cardioverter-defibrillator (ICD) electrode application were investigated in a phosphate buffered saline solution. The electrochemical interfacial proper-ties were examined by electrochemical impedance spectroscopy, and the potential and current response during ICD shock pulses were recorded by a digital oscilloscope. Changes in surface composition and structure were investigated using X-ray photoelectron spectroscopy and environmental scanning electron microscopy. When exposed to anodic 700 V shock pulses with duration of 10 ms, only Pt was stable, nano-porous carbon electrode was slightly attacked, whereas Ti and TiN electrodes suffered severe degradation. Upon cathodic shock pulsing, all the materials were stable, but Ti and TiN electrodes with a smooth surface showed evidence of hydrogen adsorption. Porous and rough electrodes produced less gas evolution compared to a smooth surfaces, due to a higher amount of charge transferred through non-Faradaic processes. The reason for this could be higher interfacial capacity due to the large surface area.

Place, publisher, year, edition, pages
2004. Vol. 49, no 22-23, 4011-4020 p.
Keyword [en]
Electrical shock pulse, Electrochemical degradation, Implantable cardioverter-defibrillator, Nano-porous carbon, Rough TiN
National Category
Physical Chemistry
URN: urn:nbn:se:kth:diva-5061DOI: 10.1016/j.electacta.2003.11.040ISI: 000222818100043ScopusID: 2-s2.0-3042751098OAI: diva2:7744
QC 20100920 QC 20110916. 54th Annual ISE Meeting. Sao Pedro, BRAZIL. SEP 01-05, 2003Available from: 2005-04-25 Created: 2005-04-25 Last updated: 2011-10-17Bibliographically approved
In thesis
1. Investigation of electrochemical properties and performance of stimulation/sensing electrodes for pacemaker applications
Open this publication in new window or tab >>Investigation of electrochemical properties and performance of stimulation/sensing electrodes for pacemaker applications
2005 (English)Doctoral thesis, comprehensive summary (Other academic)
Abstract [en]

People suffering from certain types of arrhythmia may benefit from the implantation of a cardiac pacemaker. Pacemakers artificially stimulate the heart by applying short electrical pulses to the cardiac tissue to restore and maintain a steady heart rhythm. By adjusting the pulse delivery rate the heart is stimulated to beat at desired pace. The stimulation pulses are transferred from the pacemaker to the heart via an electrode, which is implanted into the cardiac tissue. Additionally, the electrode must also sense the cardiac response and transfer those signals back to the electronics in the pacemaker for processing. The communication between the electrode and the tissue takes place on the electrode/electrolyte (tissue) interface. This interface serves as the contact point where the electronic current in the electrode is converted to ionic currents capable to operate in the body. The stimulation/sensing signals are transferred across the interface via three electrochemical mechanisms: i) non-faradaic charging/discharging of the electrochemical double layer, ii) reversible and iii) irreversible faradaic reactions. It is necessary to study the contribution of each mechanism to the total charge transferred to evaluate the pacing/sensing performance of the pacemaker electrode.

In this thesis, the electrochemical properties and performance of stimulation/sensing electrodes for pacemaker applications have been investigated by electrochemical impedance spectroscopy, cyclic voltammetry and transient electrochemical techniques. All measurements were performed in synthetic body fluid with buffer capacity. Complementary surface analysis was performed with scanning electron microscopy, energy dispersive spectroscopy and X-ray photoelectron spectroscopy.

The results reveal different interfacial behaviour and stability for electrode materials such as Pt, TiN, porous carbon, conducting oxides (RuO2 and IrO2 and mixed oxides) and porous Nb2O5 oxide. The influence of the charge/discharge rate on the electrode characteristics also has been evaluated. Although the rough and porous electrodes provide a high interfacial capacitance, the maximum capacitance cannot be fully employed at high charge/discharge rates because only a small part of the effective surface area is accessible. The benefit of pseudo-capacitive material properties on charge delivery was observed. However, these materials suffer similar limitations at high charge/discharge rate and, hence, are only utilising the surface bound pseudo-capacitive sites. Porous Nb2O5 electrodes were investigated to study the performance of capacitor electrodes. These electrodes predominantly deliver the charge via reversible non-faradaic mechanisms and hence do not produce irreversible by-products. They can deliver very high potential pulses while maintaining high impedance and, thus, charge lost by faradaic currents are kept low. By producing Nb oxide by plasma electrolysis oxidation a porous surface structure is obtained which has the potential to provide a biocompatible interface for cell adherence and growth.

This thesis covers a multidisciplinary area. In an attempt to connect diverse fields, such as electrophysiology, materials science and electrochemistry, the first chapters have been attributed to explaining fundamental aspects of the respective fields. This thesis also reviews the current opinion of pacing and sensing theory, with special focus on some areas where detailed explanation is needed for the fundamental nature of electrostimulation/sensing.

Place, publisher, year, edition, pages
Stockholm: KTH, 2005. vii, 119 p.
Physical chemistry, pacemaker electrode, interfacial property, biomaterial, electrostimulation charge transfer mechanism, electrochemical impedance spectroscopy, transient processes, plasma electrolysis anodisation, porous niobium oxide, ruthenium oxide, nano-porous carbon, iridium oxide, titanium nitride, platinum, surface roughness, porous electrode, pacing impedance, electrode polarisation, Fysikalisk kemi
National Category
Physical Chemistry
urn:nbn:se:kth:diva-176 (URN)91-7283-994-5 (ISBN)
Public defence
2005-04-29, Kollegiesalen, Administrationsbyggnaden, Valhallavägen 79, Stockholm, 14:00 (English)
QC 20101014Available from: 2005-04-25 Created: 2005-04-25 Last updated: 2012-03-14Bibliographically approved

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