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Synthesis and Crystal Structures of Di- and Trimercury Chlorogallates
KTH, Superseded Departments, Chemistry.ORCID iD: 0000-0001-6737-8233
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
2004 (English)In: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 630, no 5, 760-762 p.Article in journal (Refereed) Published
Abstract [en]

Mercury(I) chloride reacts with gallium(III) chloride in benzene/1,2-dichlorobenzene solution to give the binuclear compound Hg-2(GaCl4)(2) (1). Reduction of mercury(I) chloride with mercury in gallium(III) chloride-benzene mixture leads to the trinuclear compound Hg-3(GaCl4)(2) (2). The crystal structures of 1 and 2 were determined by single-crystal X-ray diffraction {Hg-2(GaCl4)(2): triclinic, P (1) over bar, a = 645.21(3), b = 654.44(3), c = 927.17(7) pm, alpha = 83.526(2)degrees, beta = 74.915(2)degrees, gamma = 61.863(3)degrees; Hg-3(GaCl4)(2): monoclinic, P2(1)/c, a = 715.79(1), b = 1501.59(4), c = 1421.43(4) pm, beta = 98.9798(9)degrees}.

Place, publisher, year, edition, pages
2004. Vol. 630, no 5, 760-762 p.
Keyword [en]
mercury, gallium, crystal structure, subvalent compounds
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-5108DOI: 10.1002/zaac.200400015ISI: 000221884100026Scopus ID: 2-s2.0-4644302357OAI: oai:DiVA.org:kth-5108DiVA: diva2:7873
Note
QC 20101001Available from: 2005-05-15 Created: 2005-05-15 Last updated: 2017-12-04Bibliographically approved
In thesis
1. Geometric and Electronic Structure of Metal-Metal Bonded Systems
Open this publication in new window or tab >>Geometric and Electronic Structure of Metal-Metal Bonded Systems
2005 (English)Doctoral thesis, comprehensive summary (Other scientific)
Keyword
Inorganic chemistry, Oorganisk kemi
National Category
Inorganic Chemistry
Identifiers
urn:nbn:se:kth:diva-197 (URN)91-7178-036-X (ISBN)
Public defence
2005-05-20, K1, Kemi, Teknikringen 56, Stockholm, 13:00
Opponent
Supervisors
Available from: 2005-05-15 Created: 2005-05-15 Last updated: 2012-03-21

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Rosdahl, Jan

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