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On the Structure of Sn9(4-) Cluster in Liquid and Solid State
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.ORCID iD: 0000-0001-6737-8233
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
2005 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-1948, no 14, 2888-2894 p.Article in journal (Refereed) Published
Abstract [en]

The nonastannide clusters have been investigated usingEXAFS, NMR and Raman spectroscopy as well as quantum chemical calculations explicitly considering a model cationic field and solid-state statistics. NMR spectroscopic andEXAFS results are basically identical to those previously published and consistent with a fluctional model of the cluster. The quantum chemical calculations show that there is no significant difference in energy between the two model geometries, C4v and D3h, and that the vibrational frequencies are very low, clearly indicating that the cluster is expected to be fluctional. The solid-state statistics show that both model geometries can be used to describe all known nonastannide structures with reasonable success, illustrating that the classification of the nonastannide clusters in terms of specific symmetries is entirely arbitrary.

Place, publisher, year, edition, pages
2005. no 14, 2888-2894 p.
Keyword [en]
EXAFS spectroscopy / Cluster compounds, Polyanions, Solid-state structures, Ab initio calculations
National Category
Inorganic Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-5109DOI: 10.1002/ejic.200500043ISI: 000230781400015Scopus ID: 2-s2.0-22444442431OAI: oai:DiVA.org:kth-5109DiVA: diva2:7874
Note
QC 20101011Available from: 2005-05-15 Created: 2005-05-15 Last updated: 2017-12-04Bibliographically approved
In thesis
1. Geometric and Electronic Structure of Metal-Metal Bonded Systems
Open this publication in new window or tab >>Geometric and Electronic Structure of Metal-Metal Bonded Systems
2005 (English)Doctoral thesis, comprehensive summary (Other scientific)
Keyword
Inorganic chemistry, Oorganisk kemi
National Category
Inorganic Chemistry
Identifiers
urn:nbn:se:kth:diva-197 (URN)91-7178-036-X (ISBN)
Public defence
2005-05-20, K1, Kemi, Teknikringen 56, Stockholm, 13:00
Opponent
Supervisors
Available from: 2005-05-15 Created: 2005-05-15 Last updated: 2012-03-21

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Rosdahl, Jan

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