Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Toward Industrial Grafting of Cellulosic Substrates via ARGET ATRP
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.ORCID iD: 0000-0002-8194-0058
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.ORCID iD: 0000-0002-8348-2273
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.ORCID iD: 0000-0001-7132-3251
2015 (English)In: Journal of Applied Polymer Science, ISSN 0021-8995, E-ISSN 1097-4628, Vol. 132, no 6, 41434- p.Article in journal (Refereed) Published
Abstract [en]

For the past decade, the interest in controlled grafting of cellulose has increased immensely. Surface-Initiated Atom Transfer Radical Polymerization (SI-ATRP) has attracted the most interest; however, the sensitivity of this system has so far hindered its utilization in industry. In this study, filter paper, dissolving pulp, bleached and unbleached Kraft-pulp, and chemi-thermomechanical pulp papers were grafted with methyl methacrylate, employing activators regenerated by electron transfer (ARGET) ATRP. The reactions were performed in bulk or with small amounts of aqueous solutions, with no deoxygenation performed. To further demonstrate the robustness of this method towards simpler and more industry-friendly processes, the polymerizations were conducted in glass jars with screw lids. The possibility of recycling the reaction solution was also explored. We believe his thorough study to be an important step towards industrializing the "grafting-from" concept, and the results herein can most likely be extended to other surfaces and monomers.

Place, publisher, year, edition, pages
2015. Vol. 132, no 6, 41434- p.
Keyword [en]
biopolymers and renewable polymers, cellulose and other wood products, composites, grafting, surfaces and interfaces
National Category
Polymer Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-158791DOI: 10.1002/app.41434ISI: 000345221400023Scopus ID: 2-s2.0-84912525109OAI: oai:DiVA.org:kth-158791DiVA: diva2:788020
Note

QC 20150212

Available from: 2015-02-12 Created: 2015-01-12 Last updated: 2017-12-04Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Authority records BETA

Carlmark, AnnaMalmström, EvaFogelström, Linda

Search in DiVA

By author/editor
Hansson, SusanneCarlmark, AnnaMalmström, EvaFogelström, Linda
By organisation
Fibre and Polymer Technology
In the same journal
Journal of Applied Polymer Science
Polymer Chemistry

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 262 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf