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On the nature of hydrogen bonds to platinum(II): Which interaction can predict their strength?
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology.ORCID iD: 0000-0002-1553-4027
2015 (English)In: Physical Chemistry, Chemical Physics - PCCP, ISSN 1463-9076, E-ISSN 1463-9084, Vol. 17, no 2, 812-816 p.Article in journal (Refereed) Published
Abstract [en]

The interaction between hydrogen bond donors and platinum has been analysed. Our results point to an interaction that can be entirely predicted from the d(z2) orbital energy of the platinum centre indicating strong charge transfer, with significant dispersion contribution to the bonding, very different from classical hydrogen bonds.

Place, publisher, year, edition, pages
2015. Vol. 17, no 2, 812-816 p.
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Chemical Sciences
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URN: urn:nbn:se:kth:diva-160059DOI: 10.1039/c4cp04657aISI: 000346236000009Scopus ID: 2-s2.0-84916614193OAI: oai:DiVA.org:kth-160059DiVA: diva2:792822
Note

QC 20150305

Available from: 2015-03-05 Created: 2015-02-13 Last updated: 2017-12-04Bibliographically approved

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Ahlquist, Mårten S. G.

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