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Telechelic polymers derived from natural resources as building blocks for polymer thermosets
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Coating Technology.
2015 (English)Licentiate thesis, comprehensive summary (Other academic)
Place, publisher, year, edition, pages
Stockholm: KTH Royal Institute of Technology, 2015. , 39 p.
Series
TRITA-CHE-Report, ISSN 1654-1081 ; 2015:13
National Category
Polymer Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-162128ISBN: 978-91-7595-469-1 (print)OAI: oai:DiVA.org:kth-162128DiVA: diva2:797188
Presentation
2015-03-27, K1, Teknikringen 56, Stockholm, 13:00 (English)
Opponent
Supervisors
Note

QC 20150323

Available from: 2015-03-23 Created: 2015-03-23 Last updated: 2015-03-25Bibliographically approved
List of papers
1. Polymer Thermosets from Multifunctional Polyester Resins Based on Renewable Monomers
Open this publication in new window or tab >>Polymer Thermosets from Multifunctional Polyester Resins Based on Renewable Monomers
2014 (English)In: Macromolecular Chemistry and Physics, ISSN 1022-1352, E-ISSN 1521-3935, Vol. 215, no 22, 2198-2206 p.Article in journal (Refereed) Published
Abstract [en]

The use of monomers based on natural materials as a future supply of raw materials has gained more interest in the last decade. Sources ranging from wood to plant oils and algae are exploited as alternatives to traditional fossil-based resources for the synthesis of polymeric materials. The use of these raw materials is not only of interest because of its abundance, but also in terms of price, durability, and/or biodegradability. In the present study, a series of resins utilizing a monomer derived from birch bark is prepared. The thermoset resins are formed by reacting an epoxy-functional omega-hydroxy fatty acid with methacrylate monomers using enzyme catalysis to form multifunctional resins via a one-pot synthesis. The derived oligomers are crosslinked through different polymerization routes to produce thermosets with different properties and/or functionalities. This approach allows natural-based resins with tuned functionalities and mechanical and thermal properties to be obtained.

Keyword
dual curing, enzymatic catalysis, renewable monomers, suberin
National Category
Polymer Technologies
Identifiers
urn:nbn:se:kth:diva-158419 (URN)10.1002/macp.201400192 (DOI)000345444200006 ()2-s2.0-84913620344 (Scopus ID)
Note

QC 20150107

Available from: 2015-01-07 Created: 2015-01-07 Last updated: 2017-12-05Bibliographically approved
2. Oxetane terminated telechelic epoxyfunctional-polyesters as cationically polymerizable thermoset resins - tuning the reactivity with structural design
Open this publication in new window or tab >>Oxetane terminated telechelic epoxyfunctional-polyesters as cationically polymerizable thermoset resins - tuning the reactivity with structural design
(English)Manuscript (preprint) (Other academic)
National Category
Polymer Chemistry
Identifiers
urn:nbn:se:kth:diva-162186 (URN)
Note

QS 2015

Available from: 2015-03-23 Created: 2015-03-23 Last updated: 2015-03-23Bibliographically approved

Open Access in DiVA

Licentiate Thesis(1616 kB)130 downloads
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CiteExportLink to record
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Citation style
  • apa
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  • de-DE
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  • Other locale
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Output format
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