Electrochemical driven water oxidation by molecular catalysts in situ polymerized on the surface of graphite carbon electrode
2015 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, Vol. 51, no 37, 7883-7886 p.Article in journal (Refereed) Published
A simple strategy to immobilize highly efficient ruthenium based molecular water-oxidation catalysts on the basal-plane pyrolytic graphite electrode (BPG) by polymerization has been demonstrated. The electrode 1@BPG has obtained a high initial turnover frequency (TOF) of 10.47 s-1 at ∼700 mV overpotential, and a high turnover number (TON) up to 31600 in 1 h electrolysis.
Place, publisher, year, edition, pages
2015. Vol. 51, no 37, 7883-7886 p.
IdentifiersURN: urn:nbn:se:kth:diva-167712DOI: 10.1039/c5cc00242gISI: 000353639300026ScopusID: 2-s2.0-84928537759OAI: oai:DiVA.org:kth-167712DiVA: diva2:815897
FunderSwedish Research CouncilKnut and Alice Wallenberg FoundationSwedish Energy Agency
QC 201506022015-06-022015-05-222015-09-16Bibliographically approved