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Corrosion of copper in distilled water without O2 and the detection of produced hydrogen
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Surface and Corrosion Science.
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2015 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 95, 162-167 p.Article in journal (Refereed) Published
Abstract [en]

This paper reports on hydrogen pressures measured during ~19,000. h immersion of copper in oxygen-free liquid distilled water. Copper corrosion products have been examined ex-situ by SEM and characterized by XPS and SIMS. XPS strongly indicates a corrosion product containing both oxygen and hydrogen. SIMS shows that oxygen is mainly present in the outer 0.3. μm surface region and that hydrogen penetrates to depths well below the corrosion product. Thermal desorption spectroscopy shows that the reaction product formed near room-temperature is less stable than that formed in air at 350. °C.

Place, publisher, year, edition, pages
2015. Vol. 95, 162-167 p.
Keyword [en]
A. Copper, B. AES, B. SIMS, B. XPS, C. Hydrogen absorption, C. Oxidation
National Category
Corrosion Engineering
Identifiers
URN: urn:nbn:se:kth:diva-166896DOI: 10.1016/j.corsci.2015.03.009ISI: 000354001400017Scopus ID: 2-s2.0-84927570949OAI: oai:DiVA.org:kth-166896DiVA: diva2:818026
Funder
Swedish Radiation Safety Authority
Note

QC 20150608

Available from: 2015-06-08 Created: 2015-05-21 Last updated: 2017-12-04Bibliographically approved

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