Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Rotational Doppler Effect: A Probe for Molecular Orbitals Anisotropy
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology. Shandong University of Science and Technology, China.
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology. Synchrotron SOLEIL, L'Orme des Merisiers, France.
KTH, School of Biotechnology (BIO), Theoretical Chemistry and Biology. Synchrotron SOLEIL, L'Orme des Merisiers, France.ORCID iD: 0000-0003-1269-8760
Show others and affiliations
2015 (English)In: Journal of Physical Chemistry Letters, ISSN 1948-7185, E-ISSN 1948-7185, Vol. 6, no 9, 1568-1572 p.Article in journal (Refereed) Published
Abstract [en]

The vibrationally resolved X-ray photoelectron spectra of X-2 Sigma(+)(g)(3 sigma(-1)(g)) and B-2 Sigma(+)(u)(2 sigma(-1)(u)) states of N-2(+) were recorded for different photon energies and orientations of the polarization vector. Clear dependencies of the spectral line widths on the X-ray polarization as well as on the symmetry of the final electronic states are observed. Contrary to the translational Doppler, the rotational Doppler broadening is sensitive to the photoelectron emission anisotropy. On the basis of theoretical modeling, we suggest that the different rotational Doppler broadenings observed for gerade and ungerade final states result from a Young's double-slit interference phenomenon.

Place, publisher, year, edition, pages
2015. Vol. 6, no 9, 1568-1572 p.
Keyword [en]
molecular orbitals anisotropy, rotational Doppler effect, translational Doppler effect, X-ray, Young's double slit interference
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-169268DOI: 10.1021/acs.jpclett.5b00325ISI: 000355014900013Scopus ID: 2-s2.0-84928991263OAI: oai:DiVA.org:kth-169268DiVA: diva2:822087
Funder
EU, FP7, Seventh Framework Programme, 252781Swedish Research Council
Note

QC 20150616

Available from: 2015-06-16 Created: 2015-06-12 Last updated: 2017-12-04Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Authority records BETA

Kimberg, Victor

Search in DiVA

By author/editor
Miao, QuanGel'mukhanov, FarisKimberg, VictorSun, Yu-Ping
By organisation
Theoretical Chemistry and Biology
In the same journal
Journal of Physical Chemistry Letters
Chemical Sciences

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 31 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf