Change search
ReferencesLink to record
Permanent link

Direct link
Residual Metallic Contamination of Transferred Chemical Vapor Deposited Graphene
Show others and affiliations
2015 (English)In: ACS Nano, ISSN 1936-0851, E-ISSN 1936-086X, Vol. 9, no 5, 4776-4785 p.Article in journal (Refereed) Published
Abstract [en]

Integration of graphene with Si microelectronics is very appealing by offering a potentially broad range of new functionalities. New materials to be integrated with the Si platform must conform to stringent purity standards. Here, we investigate graphene layers grown on copper foils by chemical vapor deposition and transferred to silicon wafers by wet etching and electrochemical delamination methods with respect to residual submonolayer metallic contaminations. Regardless of the transfer method and associated cleaning scheme, time-of-flight secondary ion mass spectrometry and total reflection X-ray fluorescence measurements indicate that the graphene sheets are contaminated with residual metals (copper, iron) with a concentration exceeding 10(13) atoms/cm(2). These metal impurities appear to be partially mobile upon thermal treatment, as shown by depth profiling and reduction of the minority charge carrier diffusion length in the silicon substrate. As residual metallic impurities can significantly alter electronic and electrochemical properties of graphene and can severely impede the process of integration with silicon microelectronics, these results reveal that further progress in synthesis, handling, and cleaning of graphene is required to advance electronic and optoelectronic applications.

Place, publisher, year, edition, pages
2015. Vol. 9, no 5, 4776-4785 p.
Keyword [en]
CVD graphene, transfer, metallic contaminations, ToF-SIMS, TXRF
National Category
Other Engineering and Technologies
URN: urn:nbn:se:kth:diva-169969DOI: 10.1021/acsnano.5b01261ISI: 000355383000014PubMedID: 25853630ScopusID: 2-s2.0-84930638459OAI: diva2:826558
EU, European Research Council, INTEGRADE (307311)EU, FP7, Seventh Framework Programme, 604391

QC 20150625

Available from: 2015-06-25 Created: 2015-06-25 Last updated: 2015-06-25Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textPubMedScopus

Search in DiVA

By author/editor
Vaziri, SamÖstling, Mikael
By organisation
Integrated Devices and Circuits
In the same journal
ACS Nano
Other Engineering and Technologies

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 30 hits
ReferencesLink to record
Permanent link

Direct link