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Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)
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2015 (English)In: Pure and Applied Chemistry, ISSN 0033-4545, E-ISSN 1365-3075, Vol. 87, no 11-12, 1139-1150 p.Article in journal (Refereed) PublishedText
Abstract [en]

Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 degrees C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pK(a)'s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.

Place, publisher, year, edition, pages
Walter de Gruyter, 2015. Vol. 87, no 11-12, 1139-1150 p.
Keyword [en]
aqueous solutions, chemical equilibrium, chemical thermodynamics, inorganic chemistry, IUPAC Physical and Biophysical Chemistry Division, oxidation, radicals, standard electrode potentials
National Category
Chemical Sciences
URN: urn:nbn:se:kth:diva-180120DOI: 10.1515/pac-2014-0502ISI: 000366057300006ScopusID: 2-s2.0-84949981405OAI: diva2:894103

QC 20160114

Available from: 2016-01-14 Created: 2016-01-07 Last updated: 2016-01-14Bibliographically approved

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Merenyi, Gabor
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Applied Physical Chemistry
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