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Biomass oxygen/steam gasification in a pressurized bubbling fluidized bed: Agglomeration behavior
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Chemical Technology.
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Chemical Technology.ORCID iD: 0000-0002-2460-914X
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Chemical Technology.ORCID iD: 0000-0002-6326-4084
2016 (English)In: Applied Energy, ISSN 0306-2619, E-ISSN 1872-9118, Vol. 172, 230-250 p.Article in journal (Refereed) PublishedText
Abstract [en]

In this study, the anti-agglomeration abilities of Ca- and Mg-containing bed materials, including dolomite and magnesite, in a pressurized bubbling fluidized bed gasifier using pine pellets and birch chips as feedstock, is investigated. The most typical bed material-silica sand-was also included as a reference for comparison. The sustainability of the operation was evaluated via analyzing the temperatures at different levels along the bed height. During the performances, the aim was to keep the temperature at the bottom zone of the reactor at around 870 °C. However, the success highly depends on the bed materials used in the bed and the temperature can vary significantly in case of agglomeration or bad mixing of bed materials and char particles. Both Glanshammar and Sala dolomites performed well with no observed agglomeration tendencies. In case of magnesite, the bed exhibited a high agglomeration tendency. Silica sand displayed the most severe agglomeration among all bed materials, even when birch chips with a low silica content was fed at a relatively low temperature. The solid samples of all the bed materials were inspected by light microscopy and Scanning Electron Microscopy (SEM). The Energy Dispersive Spectroscopy (EDS) detector was used to detect the elemental distribution in the surface. The crystal chemical structure was analyzed using X-ray Diffraction (XRD). Magnesite agglomerates glued together by big molten ash particles. There was no coating layer detected on magnesite particles at bed temperatures - below 870 °C. But when the temperature was above 1000 °C, a significant amount of small molten ash particles was deposited on the magnesite particles, indicating a pronounced tendency for formation of a coating layer in case of long-term operation. An increasing trend of Si on the surface of dolomite particles was observed. Simultaneously, potassium deposition on the surface is not obvious. The analyses, based on the XRD diffraction and the K2O-SiO2-MgO and K2O-SiO2-CaO ternary diagrams, suggest that the observed decreases in the risks for agglomeration using dolomite, cannot be attributed to formation of alkali-containing compounds with higher melting points, but to the reaction between dolomite and silica, consuming a considerable portion of silicon and thus hinder the formation of low-melting potassium silicate, as well as its ability to stabilize the temperatures under pressurized conditions.

Place, publisher, year, edition, pages
Elsevier, 2016. Vol. 172, 230-250 p.
Keyword [en]
Agglomeration, Calcium, Dolomite, Gasification, Magnesite, Silica sand
National Category
Energy Engineering
Identifiers
URN: urn:nbn:se:kth:diva-186929DOI: 10.1016/j.apenergy.2016.03.106ISI: 000376790400020ScopusID: 2-s2.0-84962136699OAI: oai:DiVA.org:kth-186929DiVA: diva2:931201
Note

QC 20160526

Available from: 2016-05-26 Created: 2016-05-16 Last updated: 2016-06-28Bibliographically approved

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Zhou, ChunguangRosén, ChristerEngvall, Klas
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