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A recyclable and regenerable magnetic chitosan absorbent for dye uptake
KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Polymer Technology. Sichuan Univ, Peoples R China.
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2016 (English)In: Carbohydrate Polymers, ISSN 0144-8617, E-ISSN 1879-1344, Vol. 150, 201-208 p.Article in journal (Refereed) PublishedText
Abstract [en]

A recyclable and regenerable magnetic polysaccharide absorbent for methylene blue (MB) removal was prepared by coating magnetic polyethyleneimine nanoparticles (PEI@MNPs) with sulfonated chitosan (SCS) and further cross -linked with glutaraldehyde. The driving force for coating is the electrostactic interaction between positively charged PEI and negatively charged SCS. Infrared spectra, zeta potential, thermal gravimetric analysis and X-ray diffraction demonstrated the successful synthesis of magnetic polysaccharide absorbent. The self-assembly of polysaccharide with magnetic nanopartices did not alter the saturation magnetization value of the absorbent confirmed by vibrating sample magnetometer. The nanoparticles showed fast removal (about 30 min reached equilibrium) of MB. In particular, the removal ability of MB after desorption did not reduce, demonstrating an excellent regeneration ability. Our study provides new insights into utilizing polysaccharides for environmental remediation and creating advanced magnetic materials for various promising applications.

Place, publisher, year, edition, pages
2016. Vol. 150, 201-208 p.
Keyword [en]
Magnetic chitosan absorbent, Recyclable, Regenerable, Self-assembly, Post-crosslinking
National Category
Polymer Technologies
Identifiers
URN: urn:nbn:se:kth:diva-189782DOI: 10.1016/j.carbpol.2016.05.037ISI: 000377971800025PubMedID: 27312630ScopusID: 2-s2.0-84971013879OAI: oai:DiVA.org:kth-189782DiVA: diva2:949566
Note

QC 20160721

Available from: 2016-07-21 Created: 2016-07-15 Last updated: 2016-07-21Bibliographically approved

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Zhao, Weifeng
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