Structure determination through measurements of Doppler-split Augerresonances in fixed-in-space molecules
2004 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 69, no 2, 020501(R)- p.Article in journal (Refereed) Published
Auger resonances of dissociating atoms in randomly oriented molecules experience large electronic Dopplershifts. We predict that when fixed-in-space molecules are considered there will appear extra Doppler resonancesresulting from the diffractional scattering of the Auger electrons by the surrounding atoms. Theseresonances show sharp maxima in bond directions, something that makes them very promising as probes forlocal molecular structure using current energy- and angular-resolved electron-ion coincidence experiments.
Place, publisher, year, edition, pages
2004. Vol. 69, no 2, 020501(R)- p.
FEMTOSECOND DISSOCIATION, ANGULAR-DISTRIBUTION, ELECTRONS, SPECTRA, DECAY
IdentifiersURN: urn:nbn:se:kth:diva-5492DOI: 10.1103/PhysRevA.69.020501ISI: 000189386300003ScopusID: 2-s2.0-1942540520OAI: oai:DiVA.org:kth-5492DiVA: diva2:9875
QC 201009062006-03-152006-03-152012-04-04Bibliographically approved