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  • 1.
    Alvarez Ruiz, Jesus
    et al.
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Melero-Garcia, Emilio
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Kivimäki, Antti
    Coreno, M.
    Erman, Peter
    KTH, School of Engineering Sciences (SCI), Physics.
    Rachlew, Elisabeth
    KTH, School of Engineering Sciences (SCI), Physics.
    Richter, R.
    Synchrotron radiation induced fluorescence spectroscopy of SF62005In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 38, p. 387-Article in journal (Refereed)
    Abstract [en]

    The fluorescence of gaseous SF6 was investigated after excitation with 25-80eV synchrotron radiation photons. The total UV-Vis-near IR fluorescence yield was recorded and interpreted in terms of inner valence excitations/ionizations and double excitations in SF6. Dispersed fluorescence measurements in the 400-1000 nm spectral range reveal excited S, S+, F and F+ fragments as solely responsible for the emission. The fluorescence intensity of some of the observed atomic transitions was monitored as a function of the excitation energy. Single, double and triple excitations as well as direct ionizations and shake-ups are proposed as the triggering processes responsible for the creation of the emitting fragments.

  • 2.
    García, Emilio Melero
    et al.
    KTH, Superseded Departments, Physics.
    Álvarez Ruiz, Jesús
    KTH, Superseded Departments, Physics.
    Erman, Peter
    KTH, Superseded Departments, Physics.
    Kivimäki, Antti Eerik
    KTH, Superseded Departments, Physics.
    Rachlew-Källne, Elisabeth
    KTH, Superseded Departments, Physics.
    Rius Riu, Jaume
    KTH, Superseded Departments, Physics.
    Stankiewicz, Marek
    KTH, Superseded Departments, Physics.
    Veseth, V.
    Neutral dissociation of superexcited states in nitric oxide2003In: Chemical Physics, ISSN 0301-0104, E-ISSN 1873-4421, Vol. 293, no 1, p. 65-73Article in journal (Refereed)
    Abstract [en]

    Near-infrared dispersed fluorescence measurements of 13 different atomic multiplets of neutral atomic fragments from photon induced neutral dissociation processes in NO are reported. For excitation of the molecules narrow band synchrotron photons of energy 17.2-25.8 eV were used. Neither Rydberg series nor other molecular states in NO known so far can account for the collected data. From ab initio calculations we try to obtain more information regarding the NO precursor states, and the mechanism behind the observed neutral dissociation.

  • 3.
    Kivimäki, Antti
    et al.
    KTH, Superseded Departments, Physics.
    Alvarez Ruiz, Jesus
    KTH, Superseded Departments, Physics.
    Erman, Peter
    KTH, Superseded Departments, Physics.
    Hatherly, Paul
    Melero Garcia, Emilio
    KTH, Superseded Departments, Physics.
    Rachlew, Elisabeth
    KTH, Superseded Departments, Physics.
    Rius i Riu, Jaume
    KTH, Superseded Departments, Physics.
    Stankiewicz, Marek
    An energy resolved electron-ion coincidence study near the S 2p thresholds of the SF6 molecule2003In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 36, no 4, p. 781-791Article in journal (Refereed)
    Abstract [en]

    The fragmentation dynamics of the SF6 molecule following the excitations of S 2p electrons into unoccupied molecular orbitals has been studied using the energy-resolved electron-ion coincidence technique. Fragmentation patterns were found to depend on the particular excitation and on the electronic state of the molecular ion. The spectator resonant Auger decay at the 2p --> 6a(1g) resonance induces changes in the ion distributions as compared to direct photoionization. Furthermore, coincidence spectra related to the same Auger structure display different ion abundances at the 2t(2g) and 4e(g) shape resonances. Differences were also found in the Auger decay spectra. These findings give further support for the previously suggested many-electron character of the 4e(g) shape resonance.

  • 4. Kivimäki, Antti
    et al.
    Coreno, M.
    Richter, R.
    Alvarez Ruiz, Jesus
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Melero Garcia, Emilio
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    De Simone, M.
    Feyer, V.
    Vall Llosera, Gemma
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Prince, K. C
    Fluorescence emission following core excitations in the water molecule2006In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 39, no 5, p. 1101-1112Article in journal (Refereed)
    Abstract [en]

    Photon-induced fluorescence spectroscopy has been used to study the fragmentation of the water molecule at the O 1s is edge. Fluorescence emission has been observed from the neutral fragments H, O and OH as well as from the ionic fragments O+ and OH+. The extracted fluorescence yields of the H Lyman-alpha emission and O 2p(3)(S-4)3p(P-3) -> 2p(3)(S-4)3s(S-3) transitions show the same structures as the total ion yield spectrum but with different relative intensities. The most intense fluorescence emission is restricted to the region of the core excitations, while above the O 1s ionization limit the signal is much weaker (in the case of H) or below the detection limit (O, OH and OH+). The fluorescence emission is concluded to follow from the following general cascade: the core-excited states decay by resonant Auger transitions, the final states reached undergo dissociation into ionic and neutral fragments, and fluorescence occurs from excited fragments. In the case of the OH (A(2)Sigma(+) -> X-2 Pi) emission, the decay of core-excited states through soft x-ray emission may also be responsible for the observed fluorescence.

  • 5.
    Melero Garcia, Emilio
    et al.
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Alvarez Ruiz, Jesus
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Menmuir, Sheena
    KTH, School of Engineering Sciences (SCI), Physics.
    Rachlew, Elisabet
    KTH, School of Engineering Sciences (SCI), Physics.
    Erman, Peter
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Kivimäki et al., Antti
    Fluorescence study of doubly excited states of molecular hydrogen2006In: Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, E-ISSN 1361-6455, Vol. 39, no 2, p. 205-213Article in journal (Refereed)
    Abstract [en]

    Photodissociation of molecular hydrogen has been investigated by means of fluorescence spectroscopy using synchrotron radiation. Balmer-alpha emission from atomic hydrogen photofragments was collected in the 20-55 eV excitation energy range. Experimental data are interpreted in terms of excitation and fragmentation of neutral doubly excited states and excited ionic states with the aid of recent theoretical model calculation.

  • 6.
    Melero Garcia, Emilio
    et al.
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Kivimäki, Antti
    Pettersson, L. M.
    KTH, School of Engineering Sciences (SCI), Physics.
    Alvarez Ruiz,, Jesús
    KTH, School of Engineering Sciences (SCI), Physics, Atomic and Molecular Physics.
    Coreno, M.
    De Simone, M.
    Richter, R.
    Prince, K. C.
    Fluorescence Emission of Excited Hydrogen Atoms after Core Excitation of Water Vapor2006In: Physical Review Letters, ISSN 0031-9007, E-ISSN 1079-7114, Physical review letters, Vol. 96, p. 063003-Article in journal (Refereed)
    Abstract [en]

    The Balmer emission from atomic hydrogen has been recorded across the resonances at the oxygen K edge of the water molecule using synchrotron radiation excitation. The emission is observed to be strongest at excitations to Rydberg resonances. The observations are interpreted using a qualitative model for the dynamics of the core-to-Rydberg excited molecule. The model links the quantum state of the core-excited water molecule via resonant Auger decay and subsequent dissociation to the state of the fluorescing hydrogen atom.

  • 7. Ruiz, J. M.
    et al.
    Erman, Peter
    KTH, Superseded Departments, Physics.
    Kivimäki, Antti
    KTH, Superseded Departments, Physics.
    Garcia, E. M.
    Rachlew, Elisabeth
    KTH, Superseded Departments, Physics.
    Stankiewicz, M.
    Selective excitation of the np sigma(1)Sigma(+)(u) and np pi(1)Pi(u) to E,F (1)Sigma(+)(g) emission systems in molecular hydrogen using synchrotron radiation2004In: Chemical Physics Letters, ISSN 0009-2614, E-ISSN 1873-4448, Vol. 388, no 03-jan, p. 31-35Article in journal (Refereed)
    Abstract [en]

    The npsigma(1)Sigma(u)(+) and nppi(1)Pi(u) states in H-2 have been selectively excited using monoenergetic synchrotron light in the range 14.4-15.5 eV and the subsequent emission was observed using a grating spectrometer. In total 22 well separated bands of the npsigma(1)Sigma(u)(divided by) and nppi(1)Pi(u) to E,F (1)Sigma(g)(divided by) systems (n = 3-7) were observed and rotationally analysed. The intensities of the P and R branches relative to the Q branch vary strongly in the nppi to EF bands confirming the existence of predissociations of a large number of nppi(1)Pi(divided by) levels. Energy levels of the E,F (1) Sigma(g)(divided by) state (v(EF) = 0, 1, 3, 6-10) are obtained which confirm earlier determinations from other H-2 experiments.

  • 8. Stankiewicz, M.
    et al.
    Riu, Jaume Rius I.
    KTH, Superseded Departments, Physics.
    Ruiz, J. Alvarez
    KTH, Superseded Departments, Physics.
    Erman, Peter
    KTH, Superseded Departments, Physics.
    Hatherly, P.
    Kivimaki, Antti
    KTH, Superseded Departments, Physics.
    Garcia, E. Melero
    KTH, Superseded Departments, Physics.
    Rachlew, Elisabeth
    KTH, Superseded Departments, Physics.
    Relaxation dynamics of SF6 studied by energy-resolved electron ion coincidence technique2004In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, E-ISSN 1873-2526, Vol. 137-40, p. 369-375Article in journal (Refereed)
    Abstract [en]

    The mass spectra from the SF6 molecule acquired by energy-resolved electron ion coincidence (EREICO) technique using (1t(1g) + [5t(1u),1t(2u)]), (3e(g) + 1t(2g)), 4t(1u), and 5a(1g) electrons after both valence and S 2p(-1) 6a(1g) core excitation reveal a strong selectivity in the dissociation from these states. From the comparison of the obtained spectra, the influence of the core-excited state in the relaxation pathway of the molecule is studied. The S 2p --> 6a(1g) core excitation does not affect the relaxation dynamics after participator Auger decay to the (1t(1g) + [5t(1u),1t(2u)])(-1) and (4t(1u))(-l) states, but it alters the relaxation dynamics after participator Auger decay to the (3e(g) + 1t(2g))(-1) and (5a(1g))(-1) states with respect to the decay processes after direct excitation of the same orbitals. These observations point to core excitation induced dissociation in the SF6 molecule.

  • 9. Stankiewicz, Marek
    et al.
    Melero García, Emilio
    KTH, Superseded Departments, Physics.
    Álvarez Ruiz, Jesus
    KTH, Superseded Departments, Physics.
    Eman, Peter
    KTH, Superseded Departments, Physics.
    Hathery, Paul
    Kivimäki, Antti
    KTH, Superseded Departments, Physics.
    Rachlew, Elisabeth
    KTH, Superseded Departments, Physics.
    Rius i Riu, Jaume
    KTH, Superseded Departments, Physics.
    Experimental station for gas phase fluorescence spectroscopy2004In: Review of Scientific Instruments, ISSN 0034-6748, E-ISSN 1089-7623, Vol. 75, no 7, p. 2402-2408Article in journal (Refereed)
    Abstract [en]

    The details of an experimental setup for gas phase atomic and molecular fluorescence measurements using synchrotron radiation are described in this article. The most significant part of the apparatus is an optical arrangement, which allows for simultaneous measurements of dispersed as well as total fluorescence intensity using an effusive gas jet and an inbuilt gas cell assembled in a convenient plug and measure configuration. The first measurements concerning fluorescence of the N-2 molecule around the N 1s edge obtained with this setup are presented.

1 - 9 of 9
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  • harvard1
  • ieee
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  • en-US
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