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  • 1.
    Dongfang, Li
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Wood cellulose activation dissolution, and hydrophobization2015Doctoral thesis, comprehensive summary (Other academic)
  • 2.
    Ek, Monica
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Chirat, Christine
    Fogelstrom, Linda
    Iversen, Tommy
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Malmström, Eva
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Coating Technology.
    Norström, Emelie
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Coating Technology.
    Sixta, Herbert
    Testova, Lidia
    Toivari, Terhi
    Wawro, Dariusz
    WOBAMA: wood based materials and fuels2014In: Cellulose Chemistry and Technology, ISSN 0576-9787, Vol. 48, no 9-10, p. 773-779Article in journal (Refereed)
    Abstract [en]

    WOBAMA - Wood Based Materials and Fuels is a biorefinery oriented scientific research project supported by Wood Wisdom-Net Research Programme and ERA-NET Bioenergy. In this project, the wood based raw materials were converted to a range of value added products through unconventional techniques. So far, many demonstrators have been prepared, such as the dissolving pulps with high cellulose content, the regenerated cellulose films with high tenacity, the hydrophobic materials based on cellulose and birch bark suberin, as well as the adhesives based on polysaccharides.

  • 3.
    Ek, Monica
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Henschen, Jonatan
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Esterification and hydrolysis of cellulose using oxalic acid dihydrate in a solvent-free reaction suitable for preparation of surface-functionalised cellulose nanocrystals with high yield2017In: Green Chemistry, ISSN 1463-9262, E-ISSN 1463-9270, Vol. 19, p. 5564-5567Article in journal (Refereed)
    Abstract [en]

    A one-pot esterification and hydrolysis of cellulose was carried outby treating cellulose fibres with molten oxalic acid dihydrate. Eachcellulose oxalate had a free carboxyl content above 1.2 mmol g−1and an average molecular weight of approximately 40 kDa.Aqueous suspensions of the oxalates were sonicated to preparecellulose nanocrystals with a gravimetric yield of 80.6%

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  • 4.
    Ek, Monica
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology. KTH, Fibre & Polymer Technol, Stockholm, Sweden..
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology. Royal Inst Technol, Fiber & Polymer Technol, Stockholm, Sweden..
    Le Normand, Myriam
    Galderma, Uppsala, Sweden..
    WOBAMA wood based materials based on bark2016In: Abstracts of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 251Article in journal (Other academic)
  • 5.
    Guo, Lifang
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Lennholm, Helena
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Zhai, H.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Structural and functional modification of cellulose nanofibrils using graft copolymerization with glycidyl methacrylate by Fe 2+ –thiourea dioxide–H 2 O 2 redox system2019In: Cellulose, ISSN 0969-0239, E-ISSN 1572-882X, Vol. 26, no 8, p. 4853-4864Article in journal (Refereed)
    Abstract [en]

    Abstract: To graft epoxy and ester functional groups onto cellulose nanofibrils (CNFs) and to overcome their poor hydrophobicity, we studied the modification of CNFs using graft copolymerization with glycidyl methacrylate (GMA) by a Fe 2+ –thiourea dioxide–H 2 O 2 initiator system (Fe 2+ –TD–H 2 O 2 ) in aqueous solution. The synthesized poly (GMA)-grafted CNF (CNF-g-PGMA) was characterized by FTIR, AFM, XRD, water contact angle, and TGA. GMA was successfully grafted onto the CNFs by Fe 2+ –TD–H 2 O 2 , the epoxy groups and ester groups of GMA were clearly present and intact in the CNF-g-PGMA, and TD is an important component of the initiator system under relatively mild graft conditions. CNF-g-PGMA may be an important intermediate because of its epoxy and ester functional groups. The main nanostructure of the CNFs was retained after graft copolymerization, and there were no obvious effects of graft copolymerization on the crystalline structure of the CNF backbone, although the crystalline index slightly decreased with the increased percentage of grafting. Graft copolymerization significantly modifies the CNF hydrophobicity. This strategy could extend the applications of CNFs into many areas. Graphical abstract: [Figure not available: see fulltext.]

  • 6.
    Henschen, Jonatan
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Wood Chemistry and Pulp Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Preparation of cellulose nanomaterials via cellulose oxalates2019In: Carbohydrate Polymers, ISSN 0144-8617, E-ISSN 1879-1344, Vol. 213, p. 208-216Article in journal (Refereed)
    Abstract [en]

    Nanocellulose prepared from cellulose oxalate has been discussed as an alternative to other methods to prepare cellulose nanofibrils or crystals. The current work describes the use of a bulk reaction between pulp and oxalic acid dihydrate to prepare cellulose oxalate followed by homogenization to produce nanocellulose. The prepared nanocellulose is on average 350 nm long and 3–4 nm wide, with particles of size and shape similar to both cellulose nanofibrils and cellulose nanocrystals. Films prepared from this nanocellulose have a maximum tensile stress of 140–200 MPa, strain at break between 3% and 5%, and oxygen permeability in the range of 0.3–0.5 cm 3 μm m −2 day −1 kPa −1 at 50% relative humidity. The presented results illustrate that cellulose oxalates may be a low-cost method to prepare nanocellulose with properties reminiscent of those of both cellulose nanofibrils and cellulose nanocrystals, which may open up new application areas for cellulose nanomaterials.

  • 7.
    Huang, Tianxiao
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Wood Chemistry and Pulp Technology.
    Chen, Chao
    KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Applied Process Metallurgy. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology. KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Centres, Wallenberg Wood Science Center. KTH Royal Inst Technol, Stockholm, Sweden..
    Hydrophobic and antibacterial textile fibres prepared by covalently attaching betulin to cellulose2019In: Abstracts of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 257Article in journal (Other academic)
  • 8.
    Huang, Tianxiao
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Wood Chemistry and Pulp Technology.
    Chen, Chao
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Hydrophobic and antibacterial textile fibres prepared by covalently attaching betulin to cellulose2019In: Cellulose, ISSN 0969-0239, E-ISSN 1572-882X, Vol. 26, no 1, p. 665-677Article in journal (Refereed)
    Abstract [en]

    Betulin, a natural compound extractable from the outer bark of birch, can be used to improve the properties of cellulosic textile fibres. Herein, oxidation was performed to prepare carboxyl-functionalized cellulose, which was subsequently covalently attached by betulin through esterification. The surface-modified cellulosic textile fibres showed a substantially improved hydrophobicity, as indicated by a water contact angle of 136°. Moreover, the material showed excellent antibacterial properties, as indicated by over 99% bacterial removal and growth inhibition, in both Gram-positive and Gram-negative bacterial assays. The method of surface-modification of the cellulosic materials adapted in this study is simple and, to the best of our knowledge, has not been carried out before. The results of this study prove that betulin, a side-stream product produced by forest industry, could be used in value-added applications, such as for preparing functional materials. Additionally, this modification route can be envisaged to be applied to other cellulose sources (e.g., microfibrillated cellulose) to achieve the goal of functionalization.

  • 9.
    Huang, Tianxiao
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Wood Chemistry and Pulp Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology, Wood Chemistry and Pulp Technology.
    Water repellency improvement of cellulosic textile fibers by betulin and a betulin-based copolymer2018In: Cellulose, ISSN 0969-0239, E-ISSN 1572-882X, Vol. 25, no 3, p. 2115-2128Article in journal (Refereed)
    Abstract [en]

    Betulin is a naturally abundant and hydrophobic compound in the outer bark of birch and can readily be obtained by solvent extraction. Here, solutions of betulin were used to treat cotton fabrics and improve their water repellency. Cotton fabric impregnated in a solution of betulin in ethanol showed a contact angle for water of approximately 153A degrees and reached a water repellency score of 70 according to a standard water repellency test method. A betulin-terephthaloyl chloride (TPC) copolymer was synthesized. Both betulin and betulin-TPC copolymer were characterized by nuclear magnetic resonance spectroscopy and Fourier transform infrared spectroscopy. The copolymer was characterized by size exclusion chromatography and differential scanning calorimetry. When impregnated with a solution of betulin-TPC copolymer in tetrahydrofuran, a cotton fabric showed a water contact angle of 151A degrees and also reached a water repellency score of 70. Films based on betulin and betulin-TPC copolymer were prepared and coated onto the surface of the fabrics by compression molding. These coated fabrics showed water contact angles of 123A degrees and 104A degrees respectively and each reached a water repellency score of 80.

  • 10.
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Ionic Liquids pretreatment of cellulose fiber materialsManuscript (preprint) (Other academic)
    Abstract [en]

    Cellulose is one of the most abundant biological and renewable materials in the world and is widely used in various industries. However, further expansion of the use of cellulose or cellulosic materials has been hampered by its poor solubility in common organic solvents.) But a relatively new family of solvents for cellulose has emerged. They are ionic liquids (ILs), organic salts with a low melting temperature, which makes them suitable as solvents. Moreover, ILs are non-volatile, non-toxic, non-flammable and thermally and chemically stable. Cellulose dissolved in ILs can be regenerated with water, ethanol, or acetone. In this study, the hardwood and softwood dissolving pulps were pretreated with two ILs – [C4mim+]CH3COO and [C4mim+]Cl. The impact of the pretreatment on the molecular weight distribution of the cellulose, its thermal stability, morphology and crystallinity was evaluated using analytical techniques such as size exclusion chromatography (SEC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray diffraction (XRD), and solid state cross-polarization/magic angle spinning 13C (CP/MAS) nuclear magnetic resonance (NMR).

  • 11.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Ibarra, David
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Köpcke, Viviana
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Production of Dissolving Grade Pulps from Wood and Non-Wood Paper-Grade Pulps by Enzymatic and Chemical Pretreatments2012In: Functional Materials from Renewable Sources / [ed] Liebner, F., Rosenau, T., American Chemical Society (ACS), 2012, p. 167-189Chapter in book (Refereed)
    Abstract [en]

    A raw material with high cellulose content and low content of hemicelluloses, residual lignin, extractives and minerals is required for many important applications in the pharmaceutical, textile, food and paint industries i.e. cotton and dissolving grade pulp are used. However, the high costs for the production of dissolving grade pulps has triggered interest in upgrading paper-grade pulps into dissolving pulps by selective removal of hemicelluloses and subsequent activation of the pulps. This study reports the feasibility to produce dissolving grade pulps from different wood and non-wood paper-grade pulps employing enzymatic and chemical pre-treatments. The results were compared to those of commercial bleached dissolving pulps.

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  • 12.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ibarra, David
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Köpcke, Vivianna
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Production of Dissolving Grade Pulps from Wood and Non-wood Paper Grade Pulps Using Enzymatic and Chemical Pre-treatmentsManuscript (preprint) (Other academic)
    Abstract [en]

    Cellulose is the most abundant biorenewable material, constitutes an important polymer since it is used as raw material for several products, e.g. paper and board but also cellulose-based products which have many important applications in the pharmaceutical, textile, food and paint industries. A raw material with high cellulose content and low content of hemicelluloses, residual lignin, extractives and minerals is required for the production of these products, e.g. cotton and dissolving grade pulp are used. However, the high cost production of dissolving grade pulps has aroused the possibility of upgrading paper grade pulps into dissolving pulps by selective removal of hemicelluloses and subsequent activation of the pulps. This study reports the feasibility to produce dissolving grade pulps from different wood and non-wood paper grade pulps employing enzymatic and chemical pre-treatments. The results were compared to those of commercial bleached dissolving pulps.

  • 13.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Iversen, T.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Treatment of a cellulose fiber surface with a suberin monomer-derived polymer2015In: Polymers from Renewable Resources, ISSN 2041-2479, Vol. 6, no 3, p. 75-90Article in journal (Refereed)
    Abstract [en]

    The biorefinery concept requires the development of value-added products, such as materials from biomass, including bark. Suberin is the most abundant component in birch (Betula verrucosa) outer bark and acts as a barrier against the penetration of water and external attacks from microorganisms. The aliphatic domain of suberin is rich in hydroxy fatty acids, such as cis-9,10-epoxy-18- hydroxyoctadecanoic acid. In this study, it was isolated from the outer bark of birch and polymerized to prepare polyepoxy acid (PEA), which was used to impregnate filter papers. After complete drying, PEA-loaded filter papers were placed under UV to crosslink the epoxides through cationic polymerization with a diaryliodonium salt as the photo-initiator. The crosslinking was evaluated using Fourier transform infrared (FTIR) spectroscopy and differential scanning calorimetry (DSC). The materials obtained after UV curing showed substantially increased hydrophobicity, decreased moisture absorption, increased tensile strength, and increased ductility. Field-emission scanning electron microscopy (FE-SEM) showed that the crosslinked PEA covered the surface of the cellulose fibers and filled the interstitial spaces.

  • 14.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Iversen, Tommy
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Biocomposites based on birch suberin2012In: NWBC 2012 - 4th Nordic Wood Biorefinery Conference, VTT Technical Research Centre of Finland , 2012, p. 342-343Conference paper (Refereed)
    Abstract [en]

    The suberin monomer, cis-9,10-epoxy-18-hydroxyoctadecanoic acid (epoxy fatty acid or EFA), was isolated from birch (Betula verrucosa) outer bark. The crude EFA was purified and polymerized via lipase-catalysis. The resulting polyesters were characterized by MALDI-TOF MS and SEC. Biocomposites were prepared through grafting EFA onto cellulose. The products were characterized by FTIR.

  • 15.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Iversen, Tommy
    Innventia.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Biocomposites based on birch suberin2012In: Abstracts of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 243Article in journal (Other academic)
  • 16.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Iversen, Tommy
    KTH, School of Chemical Science and Engineering (CHE), Centres, Wallenberg Wood Science Center. Innventia AB, Drottning Kristinas väg 61, SE-114 86 Stockholm, Sweden.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Hydrophobic materials based on cotton linter cellulose and an epoxy-activated polyester derived from a suberin monomer2015In: Holzforschung, ISSN 0018-3830, E-ISSN 1437-434XArticle in journal (Refereed)
    Abstract [en]

    Suberin is a natural hydrophobic material that could be used to improve the water repellency of cellulose surfaces. It is also abundant in the outer bark of birch (Betula verrucosa); birch bark is a side-stream product in Scandinavia from the forest industry, which is generally burned for energy production. A suberin monomer, cis-9,10-epoxy-18-hydroxyoctadecanoic acid, was isolated from birch outer bark and polymerized via lipase (immobilized Candida antarctica lipase B). The resulting epoxy-activated polyester was characterized by nuclear magnetic resonance (NMR) imaging, matrix-assisted laser desorption/ionization-time-of-flight mass spectrometry, and size exclusion chromatography. Then the polyester was cured with tartaric or oxalic acid, and the crosslinked polyesters were characterized by Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry. Hydrophobic materials were prepared by compression molding of polyester-impregnated cellulose sheets, and the final products were characterized by FTIR, cross-polarization magic angle spinning 13 C NMR, and field-emission scanning electron microscopy. The water contact angle was significantly increased from 0 ° for the original cellulose sheets to over 100 ° for the produced hydrophobic materials.

  • 17.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Moriana, Rosana
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    From forest residues to hydrophobic nanocomposites with high oxygen-barrier properties2016In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 31, no 2, p. 261-269Article in journal (Refereed)
    Abstract [en]

    A biorefinery of forest resources should be able to convert all components of trees, including the bark and other types of forest residues, into value-added products. Here, non-cellulosic polysaccharides (NCPs) isolated from Norway spruce bark and cellulose nanocrystals (CNCs) isolated from the logging residues of Norway spruce were mixed to prepare nanocomposites with competitive thermo-mechanical properties. Polyepoxy acid (PEA) derived from a monomer of suberin in birch bark was used as a coating on the nanocomposites to develop functional materials entirely based on forest resources. All of the PEA-coated nanocomposites were hydrophobic. At 50% and 80% relative humidity, they showed high oxygen-barrier properties that were comparable to or even better than those of some renewable materials such as xylan-, galactoglucomannan- and nanofibrillated cellulose-based films and synthetic materials such as polyvinylidene chloride and polyamide.

  • 18.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Sevastyanova, Olena
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ionic Liquids pretreatment of cellulose fiber materials for improvement of reactivity and value added applications2011In: 16th International Symposium on Wood, Fiber and Pulping Chemistry - Proceedings, ISWFPC , 2011, p. 503-510Conference paper (Refereed)
    Abstract [en]

    Cellulose is one of the most abundant biological and renewable materials in the world. The application of cellulose is widely distributed among various industries such as fiber, paper, pharmaceutical, membrane, polymer and paint. However, the utilization of cellulose or cellulosic materials has not been developed entirely because of its poor solubility in common organic solvents. Ionic liquids (ILs) are relatively new family of solvents for dissolution of cellulose. They are organic salts containing cations and anions with low melting temperature, which make them suitable for the solubilization of cellulose. Moreover, ILs are non-volatile, non-toxic, non-flammable and thermally and chemically stable. Cellulose dissolved in ILs can be regenerated with anti-solvents as water, ethanol and acetone. In this study, the pretreatment of both hardwood and softwood dissolving pulps with two ILs ([C4mim+]CH3COO- and [C4mim+]Cl-) were performed. Furthermore, the impact of treating cellulose with ILs was also evaluated by using different analytical techniques, such as size exclusion chromatography (SEC), thermal gravimetric analysis (TGA) and scanning electron microscopy (SEM).

  • 19.
    Li, Dongfang
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Sevastyanova, Olena
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Pretreatment of softwood dissolving pulp with ionic liquids2012In: Holzforschung, ISSN 0018-3830, E-ISSN 1437-434X, Vol. 66, no 8, p. 935-943Article in journal (Refereed)
    Abstract [en]

    Few Scandinavian pulp mills produce dissolving pulps; however, the demand on textile fibers is increasing. This study investigates the chemical interaction of dissolving pulp with ionic liquids (ILs), where softwood and hardwood industrial dissolving pulps were pretreated with ILs 1-butyl-3-methyl-imidazolium acetate ([C(4)mim(+)]CH3COO-) and 1-butyl-3-methyl-imdazolium chloride ([C(4)mim(+)]Cl-). Time and temperature dependence of the dissolution process as well as the impact of the pretreatment on the molecular weight properties, thermal stability, morphology, and crystallinity of the cellulose were evaluated by means of size exclusion chromatography (SEC), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), X-ray diffraction (XRD), and solid state nuclear magnetic resonance (NMR). It was shown that the dissolution of cellulosic material in ILs is a temperature-dependent process; however, the viscosity of ILs affected the efficiency of dissolution at a given temperature. Molecular weight properties were affected negatively by increased dissolution temperature, while the type of antisolvent for the regeneration had no major impact on the degree of polymerization of cellulose. Water was more efficient than ethanol for the regeneration of cellulose when performed at an elevated temperature. The pretreatment decreased the crystallinity of cellulosic material. This might lead to the increased accessibility and reactivity of cellulose.

  • 20.
    Sevastyanova, Olena
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Evaluation of Ionic Liquids as direct solvents for the manufacturing of novel products from cellulose2010Conference paper (Refereed)
  • 21.
    Zheng, Chao
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Bio-based fire retardant and its application in cellulose-based thermal insulation materials2018In: Abstracts of Papers of the American Chemical Society, ISSN 0065-7727, Vol. 255Article in journal (Other academic)
  • 22.
    Zheng, Chao
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology.
    Cellulose-fiber-based insulation materials with improved reaction-to-fire properties2017In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 32, no 3, p. 466-472Article in journal (Refereed)
    Abstract [en]

    The poor reaction-to-fire properties of cellulosic thermal insulation need to be improved to meet the safety regulations for building materials. In this study, cellulose-fiber-based insulation foams were prepared from formulations containing mechanical pulp and commercial fire retardants. Results of single-flame source tests showed that foams developed from the formulations with 20% expandable graphite (EG) or 25% synergetic (SY) fire retardants had substantially improved reaction-to-fire properties, and passed fire class E according to EN 13501-1. The results indicated that the foams could resist a small flame attack without serious flame spreading over a short period of time. Compared with the reference foam that contained no fire retardant, the peak heat release rate of the 20% EG and 25% SY foams decreased by 62% and 39% respectively when the samples were subjected to a radiance heat flux of 25 kW m-2 in a cone calorimeter, which suggested enhanced reaction-to-fire properties of these foams.

  • 23.
    Zheng, Chao
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Improving fire retardancy of cellulosic thermal insulating materials by coating with bio-based fire retardants2019In: Nordic Pulp & Paper Research Journal, ISSN 0283-2631, E-ISSN 2000-0669, Vol. 34, no 1, p. 96-106Article in journal (Refereed)
    Abstract [en]

    Sustainable thermal insulating materials produced from cellulosic fibers provide a viable alternative to plastic insulation foams. Industrially available, abundant, and inexpensive mechanical pulp fiber and recycled textile fiber provide potential raw materials to produce thermal insulating materials. To improve the fire retardancy of low-density thermal insulating materials produced from recycled cotton denim and mechanical pulp fibers, bio-based fire retardants, such as sulfonated kraft lignin, kraft lignin, and nanoclays, were coated onto sustainable insulating material surfaces to enhance their fire retardancy. Microfibrillated cellulose was used as a bio-based binder in the coating formula to disperse and bond the fire-retardant particles to the underlying thermal insulating materials. The flammability of the coated thermal insulating materials was tested using a single-flame source test and cone calorimetry. The results showed that sulfonated kraft lignin-coated cellulosic thermal insulating materials had a better fire retardancy compared with that for kraft lignin with a coating weight of 0.8 kg/m(2). Nanoclay-coated samples had the best fire retardancy and did not ignite under a heat flux of 25 kW/m(2), as shown by cone calorimetry and single-flame source tests, respectively. These cost-efficient and bio-based fire retardants have broad applications for improving fire retardancy of sustainable thermal insulating materials.

  • 24.
    Zheng, Chao
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Improving fire retardancy of cellulosic thermal insulating materials by coating with bio-based fire retardantsManuscript (preprint) (Other academic)
    Abstract [en]

    Sustainable thermal insulating materials produced from cellulosic fibers provide a viable alternative to plastic insulation foams. Industrially available, abundant, and inexpensive mechanical pulp fiber and recycled textile fiber provide potential raw materials to produce thermal insulating materials. To improve the fire retardancy of low-density thermal insulating materials produced from recycled cotton denim and mechanical pulp fibers, bio-based fire retardants, such as sulfonated kraft lignin, kraft lignin, and nanoclays, were coated onto sustainable insulating material surfaces to enhance their fire retardancy. Microfibrillated cellulose was used as a bio-based binder in the coating formula to disperse and bond the fire-retardant particles to the underlying thermal insulating materials. The flammability of the coated thermal insulating materials was tested using a single-flame source test and cone calorimetry. The results showed that sulfonated kraft lignin-coated cellulosic thermal insulating materials had a better fire retardancy compared with that for kraft lignin with a coating weight of 0.8 kg/m2. Nanoclay-coated samples had the best fire retardancy and did not ignite under a heat flux of 25 kW/m2, as shown by cone calorimetry and single- flame source tests, respectively. These cost-efficient and bio-based fire retardants have broad applications as sustainable thermal insulating materials for improved fire retardancy.

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  • 25.
    Zheng, Chao
    et al.
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Li, Dongfang
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Ek, Monica
    KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Fibre- and Polymer Technology.
    Mechanism and kinetics of thermal degradation of insulating materials developed from cellulose fiber and fire retardants2019In: Journal of thermal analysis and calorimetry (Print), ISSN 1388-6150, E-ISSN 1588-2926, Vol. 135, no 6, p. 3015-3027Article in journal (Refereed)
    Abstract [en]

    The mechanism and kinetics of thermal degradation of materials developed from cellulose fiber and synergetic fire retardant or expandable graphite have been investigated using thermogravimetric analysis. The model-free methods such as Kissinger–Akahira–Sunose (KAS), Friedman, and Flynn–Wall–Ozawa (FWO) were applied to measure apparent activation energy (Ea).The increased Ea indicated a greater thermal stability because of the formation of a thermally stable char, and the decreased Ea after the increasing region related to the catalytic reaction of the fire retardants, which revealed that the pyrolysis of fire retardant-containing cellulosic materials through more complex and multi-step kinetics. The Friedman method can be considered as the best method to evaluate the Ea of fire-retarded cellulose thermal insulation compared with the KAS and two methods. A master-plots method such as the Criado method was used to determine the possible degradation mechanisms. The degradation of cellulose thermal insulation without a fire retardant is governed by a D3 diffusion process when the conversion value is below 0.6, but the materials containing synergetic fire retardant and expandable graphite fire retardant may have a complicated reaction mechanism that fits several proposed theoretical models in different conversion ranges. Gases released during the thermal degradation were identified by pyrolysis–gas chromatography/mass spectrometry. Fire retardants could catalyze the dehydration of cellulosic thermal insulating materials at a lower temperature and facilitate the generation of furfural and levoglucosenone, thus promoting the formation of char. These results provide useful information to understand the pyrolysis and fire retardancy mechanism of fire-retarded cellulose thermal insulation.

  • 26.
    Zheng, Chao
    et al.
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Li, Dongfang
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ottenhall, Anna
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Ek, Monica
    KTH, School of Chemical Science and Engineering (CHE), Fibre and Polymer Technology, Wood Chemistry and Pulp Technology.
    Cellulose fiber based fungal and water resistant insulation materials2017In: International Journal of the Biology, Chemistry, Physics, and Technology of Wood, E-ISSN 1437-434X, Vol. 71, no 7-8, p. 633-639Article in journal (Refereed)
    Abstract [en]

    The development of thermal insulation materials from sustainable, natural fibrous materials is desirable.In the present study, cellulose fiber based insulation foams made of bleached chemi thermo mechanical pulp(CTMP) have been investigated. To improve water resistance, the foams were impregnated with hydrophobic extractives from the outer bark of birch (Betula verrucosa)and dried. The surface morphology of the foams and the distribution of the deposited particles from the extractives were observed by scanning electron microscopy (SEM).The modified foams showed improved water resistance, as they did not disintegrate after immersion in water for7 days, whereas the unmodified foam did. Compared to the unmodified foam, the modified foams absorbed 50%less moisture within 24 h. The modification had no negative effects on the thermal insulation properties, fungal resistance or compressive strength of the foams. The proposed approach is simple and can be easily integrated into plants working based on the biorefinery concept.

1 - 26 of 26
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