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  • 1.
    Adamopoulos, Othon
    et al.
    KTH, School of Information and Communication Technology (ICT), Material Physics (Closed 20120101), Functional Materials, FNM (Closed 20120101).
    Björkman, Eva
    KTH, School of Information and Communication Technology (ICT), Material Physics (Closed 20120101), Functional Materials, FNM (Closed 20120101).
    Zhang, Yu
    KTH, School of Information and Communication Technology (ICT), Material Physics (Closed 20120101), Functional Materials, FNM (Closed 20120101).
    Muhammed, Mamoun
    KTH, School of Information and Communication Technology (ICT), Material Physics (Closed 20120101), Functional Materials, FNM (Closed 20120101).
    Bog, Tassilo
    Mussmann, Lothar
    Lox, Egbert
    A nanophase oxygen storage material: Alumina-coated metal-based ceria2009In: Journal of the European Ceramic Society, ISSN 0955-2219, E-ISSN 1873-619X, Vol. 29, no 4, p. 677-689Article in journal (Refereed)
    Abstract [en]

    Nanoparticles of Ce1-xMxO2-delta (M = Ca or Zr) coated with Al2O3 with average crystallite size of 10 nm have been synthesised via solution chemistry approach under controlled chemical and hydrodynamic conditions. Their synthesis has been accomplished in three major steps: (1) simultaneous co-precipitation of cations, (2) sequential precipitation of Al(OH)(3) over the former particles and (3) calcination of the precipitated precursors to the corresponding oxides. Several compositions have been synthesised and their physicochemical properties are compared with commercial state-of-the-art material. The Al2O3-coating hinders the particles growth at high temperatures, resulting in materials with a large specific surface area and a restrain in the decrease of their oxygen storage capacity.

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