Endre søk
Begrens søket
1 - 16 of 16
RefereraExporteraLink til resultatlisten
Permanent link
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf
Treff pr side
  • 5
  • 10
  • 20
  • 50
  • 100
  • 250
Sortering
  • Standard (Relevans)
  • Forfatter A-Ø
  • Forfatter Ø-A
  • Tittel A-Ø
  • Tittel Ø-A
  • Type publikasjon A-Ø
  • Type publikasjon Ø-A
  • Eldste først
  • Nyeste først
  • Skapad (Eldste først)
  • Skapad (Nyeste først)
  • Senast uppdaterad (Eldste først)
  • Senast uppdaterad (Nyeste først)
  • Disputationsdatum (tidligste først)
  • Disputationsdatum (siste først)
  • Standard (Relevans)
  • Forfatter A-Ø
  • Forfatter Ø-A
  • Tittel A-Ø
  • Tittel Ø-A
  • Type publikasjon A-Ø
  • Type publikasjon Ø-A
  • Eldste først
  • Nyeste først
  • Skapad (Eldste først)
  • Skapad (Nyeste først)
  • Senast uppdaterad (Eldste først)
  • Senast uppdaterad (Nyeste først)
  • Disputationsdatum (tidligste først)
  • Disputationsdatum (siste først)
Merk
Maxantalet träffar du kan exportera från sökgränssnittet är 250. Vid större uttag använd dig av utsökningar.
  • 1.
    Chen, Cheng
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Liu, Peng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Gao, Jiajia
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för informations- och kommunikationsteknik (ICT), Centra, Zhejiang-KTH Joint Research Center of Photonics, JORCEP.
    Application of benzodithiophene based A-D-A structured materials in efficient perovskite solar cells and organic solar cells2016Inngår i: Nano Energy, ISSN 2211-2855, Vol. 23, s. 40-49Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    In this work, we have designed and synthesized a novel molecular material, BDT-C1, in which the core unit, benzodithiophene (BDT), was functionalized by thiophene (TP) and benzo-[c][1,2,5]-thiadiazole (BTZ) derivatives to generate extended pi-conjugation. BDT-C1 shows high hole mobility and high conductivity in its pristine form, in combination with appropriate energy level alignment with respect to [CH3NH3]PbI3 and PC70BM, qualifying the material as a good candidate for application both in perovskite solar cells (PSCs) as dopant-free hole transport material (HTM) and in OSCs as donor material. The champion PSCs based on BDT-C1 show an average conversion efficiency (PCE) of 13.4% (scan forward: 13.9%; scan backward: PCE=12.9%, scan rate: 10 mV/s). Although the average efficiency obtained is slightly lower than that of reference devices based on the well-known doped HTM Spiro-OMeTAD (13.7%), the BDT-C1 based devices exhibit better stability. Moreover, BDT-C1 as a donor material in OSCs also shows good performance in combination with PC70BM as acceptor material, and an efficiency of 6.1% was obtained. The present results demonstrate that BDT-C1 works well as both donor material in OSCs as well as dopant-free HTMs for efficient PSCs.

  • 2.
    Cheng, Ming
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Chen, Cheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Aitola, Kerttu
    Zhang, Fuguo
    Hua, Yong
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Boschloo, Gerrit
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. Dalian University of Technology (DUT), China.
    Highly Efficient Integrated Perovskite Solar Cells Containing a Small Molecule-PC70BM Bulk Heterojunction Layer with an Extended Photovoltaic Response Up to 900 nm2016Inngår i: Chemistry of Materials, ISSN 0897-4756, E-ISSN 1520-5002, Vol. 28, nr 23, s. 8631-8639Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    We demonstrate a high efficiency perovskite solar cell (PSC) integrated with a bulk heterojunction layer, based on acceptor-donor-acceptor (A-D-A) type hole transport material (HTM) and PC70BM composite, yielding improved photoresponse. Two A-D-A-structured hole transporting materials termed M3 and M4 were designed and synthesized. Applied as HTMs in PSCs, power conversion efficiencies (PCEs) of 14.8% and 12.3% were obtained with M3 and M4, respectively. The HTMs M3 and M4 show competitive absorption, but do not contribute to photocurrent, resulting in low current density. This issue was solved by mixing the HTMs with PC70BM to form a bulk heterojunction (BHJ) layer and integrating this layer into the PSC as hole transport layer (HTL). Through careful interface optimization, the (FAPbI(3))(0.85)(MAPbBr(3))(0.15)/HTM:PC70BM integrated devices showed improved efficiencies of 16.2% and 15.0%, respectively. More importantly, the incident-photon-to-current conversion efficiency (IPCE) spectrum shows that the photoresponse is extended to 900 nm by integrating the M4:PC70BM based BHJ and (FAPbI(3))(0.85)(MAPbBr(3))(0.15) layers.

  • 3.
    Cheng, Ming
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Chen, Cheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Xu, Bo
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Hua, Yong
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Zhang, Fuguo
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. Dalian University of Technology (DUT), China.
    A novel phenoxazine-based hole transport material for efficient perovskite solar cell2015Inngår i: Journal of Energy Challenges and Mechanics, ISSN 2095-4956, E-ISSN 2056-9386, Vol. 24, nr 6, s. 698-706Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Based on the previous research work in our laboratory, we have designed and synthesized a small-molecule, hole transport material (HTM) POZ6-2 using phenoxazine (POZ) as central unit and dicyanovinyl units as electron-withdrawing terminal groups. Through the introduction of a 2-ethyl-hexyl bulky chain into the POZ core unit, POZ6-2 exhibits good solubility in organic solvents. In addition, POZ6-2 possesses appropriate energy levels in combination with a high hole mobility and conductivity in its pristine form. Therefore, it can readily be used as a dopant-free HTM in perovskite solar cells (PSCs) and a conversion efficiency of 10.3% was obtained. The conductivity of the POZ6-2 layer can be markedly enhanced via doping in combination with typical additives, such as 4-tert-butylpyridine (TBP) and lithium bis(trifluoromethanesulfonyl) imide (LiTFSI). Correspondingly, the efficiency of the PSCs was further improved to 12.3% using doping strategies. Under the same conditions, reference devices based on the well-known HTM Spiro-OMeTAD show an efficiency of 12.8%.

  • 4.
    Cheng, Ming
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Li, Yuanyuan
    KTH, Skolan för kemivetenskap (CHE), Fiber- och polymerteknologi. KTH, Skolan för kemivetenskap (CHE), Centra, Wallenberg Wood Science Center.
    Liu, Peng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Zhang, Fuguo
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Hajian, Alireza
    KTH, Skolan för kemivetenskap (CHE), Fiber- och polymerteknologi. KTH, Skolan för kemivetenskap (CHE), Centra, Wallenberg Wood Science Center.
    Wang, Haoxin
    State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT–KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology (DUT), Dalian, China.
    Li, Jiajia
    State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT–KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology (DUT), Dalian, China.
    Wang, Linqin
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Yang, Xichuan
    State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT–KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology (DUT), Dalian, China.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. State Key Laboratory of Fine Chemicals, Institute of Artificial Photosynthesis, DUT–KTH Joint Education and Research Centre on Molecular Devices, Dalian University of Technology (DUT), Dalian, China.
    A Perylenediimide Tetramer-Based 3D Electron Transport Material for Efficient Planar Perovskite Solar Cell2017Inngår i: Solar RRL, ISSN 2367-198X, Vol. 1, nr 5, artikkel-id 1700046Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A perylenediimide (PDI) tetramer-based three dimensional (3D) molecular material, termed SFX-PDI4, has been designed, synthesized, and characterized. The low-lying HOMO and LUMO energy levels, high electron mobility and good film-formation property make it a promising electron transport material (ETM) in inverted planar perovskite solar cells (PSCs). The device exhibits a high power conversion efficiency (PCE) of 15.3% with negligible hysteresis, which can rival that of device based on PC61BM. These results demonstrate that three dimensional PDI-based molecular materials could serve as high performance ETMs in PSCs.

  • 5.
    Cheng, Ming
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Li, Yuanyuan
    KTH, Skolan för kemivetenskap (CHE), Fiber- och polymerteknologi. KTH, Skolan för kemivetenskap (CHE), Centra, Wallenberg Wood Science Center.
    Safdari, Majid
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Chen, Cheng
    Liu, Peng
    KTH, Skolan för industriell teknik och management (ITM), Materialvetenskap, Tillämpad materialfysik. KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi.
    Efficient Perovskite Solar Cells Based on a Solution Processable Nickel(II) Phthalocyanine and Vanadium Oxide Integrated Hole Transport Layer2017Inngår i: Advanced Energy Materials, ISSN 1614-6832, Vol. 7, nr 14, artikkel-id 1602556Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    An organic-inorganic integrated hole transport layer (HTL) composed of the solution-processable nickel phthalocyanine (NiPc) abbreviated NiPc-(OBu)(8) and vanadium(V) oxide (V2O5) is successfully incorporated into structured mesoporous perovskite solar cells (PSCs). The optimized PSCs show the highest stabilized power conversion efficiency of up to 16.8% and good stability under dark ambient conditions. These results highlight the potential application of organic-inorganic integrated HTLs in PSCs.

  • 6.
    Cheng, Ming
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi.
    Xu, Bo
    KTH, Skolan för kemivetenskap (CHE), Kemi.
    Chen, C.
    Yang, X.
    Zhang, F.
    Tan, Q.
    Hua, Yong
    KTH, Skolan för kemivetenskap (CHE), Kemi.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Phenoxazine-based small molecule material for efficient perovskite solar cells and bulk heterojunction organic solar cells2015Inngår i: Advanced Energy Materials, ISSN 1614-6832, Vol. 5, nr 8, artikkel-id 1401720Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The phenoxazine-based acceptor-donor-acceptor structured small-molecule material M1 is used either as a hole-transport material in (CH<inf>3</inf>NH<inf>3</inf>)PbI<inf>3</inf>-perovskite-based solar cells or as photoactive donor material in bulk heterojunction organic solar cells. Excellent power conversion efficiencies of 13.2% and 6.9% are achieved in these two types of photovoltaic devices, respectively.

  • 7.
    Hua, Yong
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Xu, Bo
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Liu, Peng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Chen, Hong
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Tian, Haining
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    High conductivity Ag-based metal organic complexes as dopant-free hole-transport materials for perovskite solar cells with high fill factors2016Inngår i: Chemical Science, ISSN 2041-6520, E-ISSN 2041-6539, Vol. 7, nr 4, s. 2633-2638Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Hole-transport materials (HTMs) play an important role as hole scavenger materials in the most efficient perovskite solar cells (PSCs). Here, for the first time, two Ag-based metal organic complexes (HA1 and HA2) are employed as a new class of dopant-free hole-transport material for application in PSCs. These HTMs show excellent conductivity and hole-transport mobility. Consequently, the devices based on these two HTMs exhibit unusually high fill factors of 0.76 for HA1 and 0.78 for HA2, which are significantly higher than that obtained using spiro-OMeTAD (0.69). The cell based on HA1-HTM in its pristine form achieved a high power conversion efficiency of 11.98% under air conditions, which is comparable to the PCE of the cell employing the well-known doped spiro-MeOTAD (12.27%) under the same conditions. More importantly, their facile synthesis and purification without using column chromatography makes these new silver-based HTMs highly promising for future commercial applications of PSCs. These results provide a new way to develop more low-cost and high conductivity metal-complex based HTMs for efficient PSCs.

  • 8.
    Hua, Yong
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Zhang, J.
    Xu, Bo
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Liu, Peng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Johansson, E. M. J.
    Sveinbjörnsson, K.
    Aitola, K.
    Boschloo, G.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD. Dalian University of Technology (DUT), China.
    Facile synthesis of fluorene-based hole transport materials for highly efficient perovskite solar cells and solid-state dye-sensitized solar cells2016Inngår i: Nano Energy, ISSN 2211-2855, Vol. 26, s. 108-113Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Two novel low-cost fluorene-based hole transport materials (HTMs) HT1 and HT2 as alternatives to the expensive HTM Spiro-OMeTAD have been designed and synthesized for the application in perovskite solar cells (PSCs) and solid-state dye-sensitized solar cell (ssDSCs). The two HTMs were prepared through a facile two-step reaction from cheap starting material and with a total yield higher than 90%. These HTMs exhibit good solubility and charge-transport ability. PSCs based on HT2 achieved power conversion efficiency (PCE) of 18.04% under air conditions, which is comparable to that of the cell employing the commonly used Spiro-OMeTAD (18.27%), while HT1-based cell showed a slightly worse performance with a PCE of 17.18%. For ssDSCs, the HT2-based device yielded a PCE of 6.35%, which is also comparable to that of a cell fabricated based on Spiro-OMeTAD (6.36%). We found that the larger dimensional structure and molecular weight of HT2 enable better photovoltaic performance than that of the smaller one HT1. These results show that easily synthesized fluorene-based HTMs have great potential to replace the expensive Spiro-OMeTAD for both PSCs and ssDSCs. © 2016 Elsevier Ltd.

  • 9. Li, J.
    et al.
    Yang, X.
    Yu, Z.
    Gurzadyan, G. G.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Zhang, F.
    Cong, Jiayan
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Wang, W.
    Wang, H.
    Li, X.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi.
    Wang, M.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Efficient dye-sensitized solar cells with [copper(6,6′-dimethyl-2,2′-bipyridine)2]2+/1+ redox shuttle2017Inngår i: RSC Advances, ISSN 2046-2069, E-ISSN 2046-2069, Vol. 7, nr 8, s. 4611-4615Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    The [copper(6,6′-dimethyl-2,2′-bipyridine)2]2+/1+ ([Cu(dmbp)2]2+/1+) redox couple, which possesses a distorted tetragonal geometry of a Cu(i) complex crystal and a distorted tetrahedral coordination geometry of Cu(ii) complex crystal, has been developed as a redox mediator in dye-sensitized solar cells (DSSCs). The energy of loss for dye regeneration was reduced with a very low but sufficient driving force of only 0.11 eV. A distinct increase in open-circuit voltage (VOC) was achieved and a remarkable power conversion efficiency of 10.3% was afforded at 100 mW cm−2 under AM 1.5G condition.

  • 10. Li, Jiajia
    et al.
    Yang, Xichuan
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Wang, Mei
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. Dalian Univ Technol, State Key Lab Fine Chem, DUT KTH Joint Educ & Res Ctr Mol Devices, Peoples R China.
    Phenoxazine-based panchromatic organic sensitizers for dye-sensitized solar cells2015Inngår i: Dyes and pigments, ISSN 0143-7208, E-ISSN 1873-3743, Vol. 116, s. 58-64Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A series of metal-free organic dyes LJJ101-LJJ103 composed of phenoxazine unit and indolinum carboxyl acid derivative have been synthesized for dye-sensitized solar cells. A systematic investigation has been conducted for the photology and electrochemistry properties of dyes LJJ101-LJJ103. Panchromatic spectra responses for all the three dyes have been obtained and extended to about 800 nm in near-infrared region. Compared to LJJ101, the introduction of thiophene and squaraine unit causes a red-shift absorption response for LJJ102 and LJJ103, respectively. When applied in dye-sensitized solar cells under AM 1.5 illumination, the device sensitized by LJJ103 yields the best conversion efficiency of 5.1% with a short-circuit photocurrent density of 13.7 mA/cm(2), an open-circuit photovoltage of 502 mV and a fill factor of 74.0%.

  • 11.
    Liu, Peng
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Xu, Bo
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Hua, Yong
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Aitola, K.
    Sveinbjörnsson, K.
    Zhang, J.
    Boschloo, G.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Kloo, Lars A.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Design, synthesis and application of a π-conjugated, non-spiro molecular alternative as hole-transport material for highly efficient dye-sensitized solar cells and perovskite solar cells2017Inngår i: Journal of Power Sources, ISSN 0378-7753, E-ISSN 1873-2755, Vol. 344, s. 11-14Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Two low-cost, easily synthesized π-conjugated molecules have been applied as hole-transport materials (HTMs) for solid state dye-sensitized solar cells (ssDSSCs) and perovskite solar cells (PSCs). For X1-based devices, high power conversion efficiencies (PCEs) of 5.8% and 14.4% in ssDSSCs and PSCs has been demonstrated. For X14-based devices, PCEs were improved to 6.1% and 16.4% in ssDSCs and PSCs, respectively.

  • 12.
    Xu, Bo
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Bi, Dongqin
    Hua, Yong
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Liu, Peng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Graetzel, Michael
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Hagfeldt, Anders
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD. Dalian University of Technology (DUT), China.
    A low-cost spiro[fluorene-9,9 '-xanthene]-based hole transport material for highly efficient solid-state dye-sensitized solar cells and perovskite solar cells2016Inngår i: Energy & Environmental Science, ISSN 1754-5692, E-ISSN 1754-5706, Vol. 9, nr 3, s. 873-877Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A low-cost spiro[fluorene-9,9'-xanthene] (SFX) based organic hole transport material (HTM) termed X60 was designed and synthesized using a two-step synthetic route. Devices with X60 as HTM showed high power conversion efficiencies (PCEs) amounting to 7.30% in solid-state dye-sensitized solar cells (ssDSCs) and 19.84% in perovskite solar cells (PSCs), under 100 mW cm(-2) AM1.5G solar illumination. To the best of our knowledge, this is the first example of an easily synthesized spiro-structured HTM that shows comparable performance with respect to the well-known HTM Spiro-OMeTAD in both ssDSCs and PSCs. Furthermore, the facile synthesis of X60 from commercially available starting materials makes this HTM very promising for large-scale industrial production in the future.

  • 13.
    Xu, Bo
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Gabrielsson, Erik
    Safdari, Majid
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Hua, Yong
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Tian, Haining
    Gardner, James M.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Kloo, Lars
    KTH, Skolan för kemivetenskap (CHE), Kemi, Tillämpad fysikalisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    1,1,2,2-Tetrachloroethane (TeCA) as a Solvent Additive for Organic Hole Transport Materials and Its Application in Highly Efficient Solid-State Dye-Sensitized Solar Cells2015Inngår i: Advanced Energy Materials, ISSN 1614-6832, Vol. 5, nr 10, artikkel-id 1402340Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A low-cost, chlorinated hydrocarbon solvent, 1,1,2,2-tetrachloroethane (TeCA), is used as an effective additive for the triarylamine-based organic hole-transport material, Spiro-OMeTAD, which is successfully applied in highly efficient solid-state dye-sensitized solar cells. A record power conversion efficiency of 7.7% is obtained by using the donor (D)-π-acceptor (A)-dye, LEG4, in combination with the new method of TeCA-doping of the hole-transporting material Spiro-OMeTAD.

  • 14.
    Zhang, Biaobiao
    et al.
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Daniel, Quentin
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Fan, Lizhou
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. Dalian University of Technology (DUT), China.
    Temperature dependence of electrocatalytic water oxidation: a triple device model with a photothermal collector and photovoltaic cell coupled to an electrolyzer2017Inngår i: Faraday discussions (Online), ISSN 1359-6640, E-ISSN 1364-5498, Vol. 198, s. 169-179Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A water oxidation electrocatalyst with high activity is essential for promoting the overall efficiency of an integrated water splitting device. Herein, by investigating the prominent temperature dependence of electrocatalytic water oxidation catalyzed by first row transition metal oxides, we present how to elevate the operating temperature of the electrolyzer as an effective and universal method to improve its electrocatalytic performance. Consequently, a triple device model combining a photothermal collector with a photovoltaic (PV) cell coupled to a water splitting device is proposed to realize the comprehensive and efficient utilization of solar energy: solar heat + PV + electrolyzer.

  • 15. Zhang, F.
    et al.
    Yang, X.
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi.
    Wang, W.
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. Dalian University of Technology (DUT), China.
    Boosting the efficiency and the stability of low cost perovskite solar cells by using CuPc nanorods as hole transport material and carbon as counter electrode2016Inngår i: Nano Energy, ISSN 2211-2855, Vol. 20, s. 108-116Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    Low temperature printable carbon cathode based perovskite solar cell was for the first time interfacial engineered with dopant free, nanorod-liked copper phthalocyanine (CuPc) to facilitate charge transportation. Both the CuPc and low temperature processed carbon are potentially noble metal-free and highly stable. By incorporating CuPc nanorods as hole-selective contact material, together with the printable low temperature processed carbon as cathode material, considerably high power conversion efficiency (PCE) of 16.1% was successfully obtained, which is comparable to or even a little higher than the device with state-of-the-art doped spiro-OMeTAD as HTM and noble metal Au as back electrode. Moreover, dramatically enhanced durability relative to doped-spiro-OMeTAD/Au based device was demonstrated by this newly developed device. Detailed excellent capability in accelerating charge extraction and suppressing charge recombination can be disclosed with steady state and time-resolved photoluminescence analysis and electrochemical impedance spectroscopy. To the best our knowledge, this is the highest efficiency that has been reported for PSCs based carbon counter electrode. The work presented here demonstrates an important step forwards to practical applications for PSCs, as it paves the way for developments of cost-effective, stable but still highly efficient PSCs, and offers the promise for a low-cost, mass-manufacturable technology that is compatible with current large-scale printing infrastructure.

  • 16. Zhang, Fuguo
    et al.
    Yang, Xichuan
    Cheng, Ming
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD.
    Li, Jiajia
    Wang, Weihan
    Wang, Haoxin
    Sun, Licheng
    KTH, Skolan för kemivetenskap (CHE), Kemi, Organisk kemi. KTH, Skolan för kemivetenskap (CHE), Centra, Molekylär elektronik, CMD. Dalian Univ Technol, China.
    Engineering of hole-selective contact for low temperature-processed carbon counter electrodebased perovskite solar cells2015Inngår i: Journal of Materials Chemistry A, ISSN 2050-7488, Vol. 3, nr 48, s. 24272-24280Artikkel i tidsskrift (Fagfellevurdert)
    Abstract [en]

    A cost-effective and solution processable hole transport material (HTM), TPDI (5,10,15-triphenyl-5H-diindolo[3,2-a:3',2'-c]carbazole), was synthesized and explored as a hole selective contact material in low temperature (100 degrees C) and printable processed carbon counter electrode based perovskite solar cells (PSCs) for the first time. This material demonstrated excellent thermal stability, high hole mobility and appropriate energy level alignment with CH3NH3PbI3 and carbon, which make it a potentially excellent alternative interfacial material for PSCs. By interfacial engineering with doped TPDI, the energy barrier at the CH3NH3PbI3/carbon interface was efficiently eliminated. Dramatically enhanced power conversion efficiency (PCE) of 15.5% was afforded, which is comparable to or even better than that of the reference device with 2,2',7,7'-tetrakis(N,N'-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD) as HTM under equivalent conditions. Besides, TPDI can also function well in its pristine form although the efficiency (13.6%) obtained is slightly lower than that with the device containing doped TPDI as the HTM. Moreover, these newly integrated noble metal-free, vacuum-free and cost effective PSCs exhibited excellent durability during the long term stability measurements for 30 days. The remarkable performance as well as dramatically reduced fabrication cost demonstrated by integrating TPDI as the HTM and cost effective commercial carbon as the cathode revealed their great potential in the scalable and practical application of PSCs.

1 - 16 of 16
RefereraExporteraLink til resultatlisten
Permanent link
Referera
Referensformat
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Annet format
Fler format
Språk
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Annet språk
Fler språk
Utmatningsformat
  • html
  • text
  • asciidoc
  • rtf