Long-range magnetic order in graphene has been the subject of study for many researches due to its fundamental and technological prospects. Many theoretical researches have predicted the long-range ferromagnetic exchange in porphyrin-like graphene due to doping the transition metals centers in their structures. However, the experimental observations for such structures, have been rarely reported. In the present work the ferromagnetic properties of iron doped porphyrin-like graphene (Fe-N-Gr) are experimentally considered and the results are reported. At first, the Fe-N-Gr sample is synthesized by mechanochemical mixing of Fe, N, and C sources followed by high temperature pyrolysis treatment. The sample shows the high saturation magnetization of 140 emu/gr at room temperature. Raman, XRD, and XPS results as well as microscopic images revealed that the observed ferromagnetic behavior is induced by doped Fe-N sites in graphene, however the exact microscopic origin cannot be explained and further investigation is needed.These results pave the way for the synthesis of magnetic porphyrin-like graphene with structurally deformed structure.

Magnetic droplets are a type of non-topological magnetic soliton, which are stabilised and sustained by spin-transfer torques for instance. Without this, they would collapse. Here Ahlberg et al show that by decreasing the applied magnetic field, droplets can be frozen, forming a static nanobubble Magnetic droplets are non-topological magnetodynamical solitons displaying a wide range of complex dynamic phenomena with potential for microwave signal generation. Bubbles, on the other hand, are internally static cylindrical magnetic domains, stabilized by external fields and magnetostatic interactions. In its original theory, the droplet was described as an imminently collapsing bubble stabilized by spin transfer torque and, in its zero-frequency limit, as equivalent to a bubble. Without nanoscale lateral confinement, pinning, or an external applied field, such a nanobubble is unstable, and should collapse. Here, we show that we can freeze dynamic droplets into static nanobubbles by decreasing the magnetic field. While the bubble has virtually the same resistance as the droplet, all signs of low-frequency microwave noise disappear. The transition is fully reversible and the bubble can be thawed back into a droplet if the magnetic field is increased under current. Whereas the droplet collapses without a sustaining current, the bubble is highly stable and remains intact for days without external drive. Electrical measurements are complemented by direct observation using scanning transmission x-ray microscopy, which corroborates the analysis and confirms that the bubble is stabilized by pinning.

We demonstrate how magnetic droplet soliton pairs, nucleated by two separated nanocontact (NC) spin torque oscillators, can merge into a single droplet soliton. A detailed description of the magnetization dynamics of this merger process is obtained by micromagnetic simulations: A droplet pair with a steady-state in-phase spin precession is generated through the spin-transfer torque effect underneath two separate NCs, followed by a gradual expansion of the droplets' volume and the out-phase of magnetization on the inner side of the two droplets, resulting in the droplets merging into a larger droplet. This merger occurs only when the NC separation is smaller than a critical value. A transient breathing mode is observed before the merged droplet stabilizes into a steady precession state. The precession frequency of the merged droplet is lower than that of the droplet pair, consistent with its larger size. Merged droplets can again break up into droplet pairs at high enough magnetic field with a strong hysteretic response.

The magnetization behavior, magnetic anisotropy, and domain configurations of Co/Pd multilayers with perpendicular magnetic anisotropy capped with permalloy is investigated using magnetometry, magnetic force microscopy, and ferromagnetic resonance. The thickness of the Ni80Fe20 layer in [Co/Pd](5)/NiFe (t) was varied from t = 0 to 80 nm in order to study the interplay between the anisotropy and magnetization directions of Co/Pd and NiFe. By varying the thickness of the NiFe layer, the net anisotropy changes sign, but domains with plane- normal magnetization are present even for the thickest NiFe. Ferromagnetic resonance measurements show a decrease in damping with increasing NiFe thickness. The results demonstrate how the magnetic behavior of mixed- anisotropy thin films can be controlled.

Several scientific issues concerning the latest generation read heads for magnetic storage devices, based on CoFeB/MgO/CoFeBmagnetic tunnel junctions (MTJs) are known to be controversial, including such fundamental questions as to the behavior and the role of B in optimizing the physical properties of these devices. Quantitatively establishing the internal structures of several such devices with different annealing conditions using hard x-ray photoelectron spectroscopy, we resolve these controversies and establish that the B diffusion is controlled by the capping Ta layer, though Ta is physically separated from the layer with B by several nanometers. While explaining this unusual phenomenon, we also provide insight into why the tunneling magnetoresistance (TMR) is optimized at an intermediate annealing temperature, relating it to B diffusion, coupled with our studies based on x-ray diffraction and magnetic studies.

Magnetic dissipative droplets are localized, strongly nonlinear dynamical modes excited in nanocontact spin valves with perpendicular magnetic anisotropy. These modes find potential application in nanoscale structures for magnetic storage and computation, but dissipative droplet studies have so far been limited to extended thin films. Here, numerical and asymptotic analyses are used to demonstrate the existence and properties of novel solitons in confined structures. As a nanowire's width is decreased with a nanocontact of fixed size at its center, the observed modes undergo transitions from a fully localized two-dimensional droplet into a two-dimensional droplet edge mode and then a pulsating one-dimensional droplet. These solitons are interpreted as dissipative versions of classical, conservative solitons, allowing for an analytical description of the modes and the mechanisms of bifurcation. The presented results open up new possibilities for the study of low-dimensional solitons and droplet applications in nanostructures.

The nano-scale spin torque oscillator (STO) is a compelling device for on-chip, highly tunable microwave frequency signal generation. Currently, one of the most important challenges for the STO is to increase its longer-time frequency stability by decreasing the 1/f frequency noise, but its high level makes even its measurement impossible using the phase noise mode of spectrum analyzers. Here, we present a custom made time-domain measurement system with 150MHz measurement bandwidth making possible the investigation of the variation of the 1/f as well as the white frequency noise in a STO over a large set of operating points covering 18-25GHz. The 1/f level is found to be highly dependent on the oscillation amplitude-frequency non-linearity and the vicinity of unexcited oscillation modes. These findings elucidate the need for a quantitative theoretical treatment of the low-frequency, colored frequency noise in STOs. Based on the results, we suggest that the 1/f frequency noise possibly can be decreased by improving the microstructural quality of the metallic thin films.

We report on the magnetization depth profile of a hybrid exchange-spring system in which a Co/Pd multilayer with perpendicular anisotropy is coupled to a CoFeB thin film with in-plane anisotropy. The competition between these two orthogonal anisotropies promotes a strong depth dependence of the magnetization orientation. The angle of the magnetization vector is sensitive both to the strength of the individual anisotropies and to the local exchange constant and is thus tunable by changing the thickness of the CoFeB layer and by substituting Ni for Pd in one layer of the Co/Pd stack. The resulting magnetic depth profiles are directly probed by element-specific x-ray magnetic circular dichroism of the Fe and Ni layers located at different average depths. The experimental results are corroborated by micromagnetic simulations.

Superparamagnetic, cubic single phase, ordered mesoporous copper ferrite is synthesized through confinement in nanocages of mesoporous silica. The heat generated during the reaction is conserved in the silica template pore channels, which allows the formation of copper ferrite at a relatively low processing temperature. The Jahn-Teller distortion is suppressed due to the effect of nanoconfinement and thus the high temperature phase of cubic copper ferrite is stabilized at room temperature. The particle size obtained from TEM, the crystallite size calculated from XRD and the magnetic domain size estimated from magnetization measurements are all in good agreement, manifesting the significant role of the confinement in the growth and fabrication of crystalline, single magnetic domain, nanoparticles with superparamagnetic behavior at room temperature.

Magnetic multilayer (ML) structures comprising a perpendicular magnetic anisotropy (PMA) layer coupled to an in-plane magnetic anisotropy (IMA) layer are promising materials for zero/low field operating spin-torque oscillators and bit patterned recording media. The magnetization tilt angle can be easily tuned by varying the IMA layer thickness due to the competition between PMA and IMA layers. To explore the underlying magnetization reversal mechanism and to further understand the control of tilt angle and uniformity of the magnetization, the IMA (NiFe, Co, and CoFeB)/PMA (Co/Pd MLs) exchange spring systems are systematically studied. Experimental data obtained from magnetometry show good agreement with 1-D micromagnetic simulations, allowing us to design tunable exchange coupled spring as a function of IMA thickness.