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Chanouian, S., Pitkala, J., Larsson, H. & Ersson, M. (2024). Modeling Decarburization in the AOD Converter: A Practical CFD-Based Approach With Chemical Reactions. Metallurgical and materials transactions. B, process metallurgy and materials processing science, 55(1), 480-494
Open this publication in new window or tab >>Modeling Decarburization in the AOD Converter: A Practical CFD-Based Approach With Chemical Reactions
2024 (English)In: Metallurgical and materials transactions. B, process metallurgy and materials processing science, ISSN 1073-5615, E-ISSN 1543-1916, Vol. 55, no 1, p. 480-494Article in journal (Refereed) Published
Abstract [en]

Gas-blowing technology is widely used in converter steelmaking to homogenize liquid steel and accelerate chemical reactions, with Argon oxygen decarburization (AOD) being the dominant process for stainless steelmaking. Due to the harsh environment, it is advisable to study the phenomenon using small-scale physical models and numerical simulations before conducting industrial-scale trials. This paper presents a practical computational fluid dynamics (CFD) approach for simulating the AOD process, with chemical reactions considered. This approach can simulate the entire process in a reasonable time using a standard workstation. The simulation employs a Finite Volume Method CFD approach to handle mass, momentum, and energy transfer, and a local equilibrium assumption is utilized. The study shows that a practical approach can be used to model the initial stage of decarburization in the AOD process with a reduced accuracy in mass transport calculations. The accuracy of the simulation is validated using industrial data, and good agreement is found.

Place, publisher, year, edition, pages
Springer Nature, 2024
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-367130 (URN)10.1007/s11663-023-02971-6 (DOI)001109539000002 ()2-s2.0-85177776926 (Scopus ID)
Note

QC 20250715

Available from: 2025-07-15 Created: 2025-07-15 Last updated: 2025-07-15Bibliographically approved
Chanouian, S., Larsson, H. & Ersson, M. (2023). The Importance of Mixing Time in Intensely Stirred Metallurgical Reactors: Applied on Decarburization Reactions. Metals, 13(10), Article ID 1694.
Open this publication in new window or tab >>The Importance of Mixing Time in Intensely Stirred Metallurgical Reactors: Applied on Decarburization Reactions
2023 (English)In: Metals, ISSN 2075-4701, Metals, E-ISSN 2075-4701, Vol. 13, no 10, article id 1694Article in journal (Refereed) Published
Abstract [en]

In metallurgical converter processes, numerical modeling is a useful tool for understanding the complexity of the systems. In this paper, we present a practical model that couples fluid dynamics and chemical reactions to explore the impact of mixing time on decarburization. Using computational fluid dynamics (CFD), in this study, we investigate an arbitrary metallurgical reactor with continuous oxygen supply, focusing on the Fe–C–O system. The model employs local equilibrium, a turbulence limiter, and finite volume method for mass, momentum, and energy transfer. Tracer injection points in the gas plume’s rising region exhibit faster mixing, and a comparison of reaction cases reveals distinct decarburization rates based on oxygen injection distribution and the influence of turbulence on reactions. Overall, while mixing time matters, the results show that this system is primarily governed by thermodynamics and oxygen supply, and a 270% increase in mixing time increase had a small impact on the end carbon content.

Place, publisher, year, edition, pages
MDPI AG, 2023
Keywords
mixing time, decarburization, metallurgical processes, computational fluid dynamics
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-338884 (URN)10.3390/met13101694 (DOI)001089525700001 ()2-s2.0-85175043629 (Scopus ID)
Funder
Vinnova, 2018-02386
Note

QC 20231030

Available from: 2023-10-30 Created: 2023-10-30 Last updated: 2023-11-21Bibliographically approved
Chanouian, S., Ahlin, B., Tilliander, A. & Ersson, M. (2022). A Fundamental Investigation of Decarburization Reactions in the Argon–Oxygen Decarburization Converter Using Coupled Computational Fluid Dynamics and Thermodynamics Databases. Steel Research International, 93(12), Article ID 2200156.
Open this publication in new window or tab >>A Fundamental Investigation of Decarburization Reactions in the Argon–Oxygen Decarburization Converter Using Coupled Computational Fluid Dynamics and Thermodynamics Databases
2022 (English)In: Steel Research International, ISSN 1611-3683, E-ISSN 1869-344X, Vol. 93, no 12, article id 2200156Article in journal (Refereed) Published
Abstract [en]

Metallurgical converters such as the argon–oxygen decarburization (AOD) converter generally utilize gas blowing for the mixing and refinement of liquid steel. Due to the harsh environment of the complex and opaque system, it is common practice to study the stirring of the process through physical and numerical models. Effective mixing in the bath has an important role in refinement such as decarburization and has been vividly studied before. However, high-temperature chemical reactions that also play a major role are sparsely investigated. With the help of modeling, a computational fluid dynamics model coupled with chemical reactions is developed, allowing the study of both dynamic fluid transport and chemical reactions. Herein, the chemical reactions for a single gas bubble in the AOD are investigated. The study shows that a 60 mm oxygen gas bubble rapidly reacts with the melt and is saturated with carbon in 0.2–0.25 s at low-pressure levels. The saturation time is affected by the pressure and the composition of the injected gas bubble. The impact of ferrostatic pressure on the reactions is more significant at larger depth differences. 

Place, publisher, year, edition, pages
John Wiley and Sons Inc, 2022
Keywords
argon–oxygen decarburization process, bubbles, computational fluid dynamics, coupled models, decarburization reactions, Argon, Bubble formation, Chemical reactions, Decarburization, Mixing, Oxygen, Thermodynamics, Transport properties, Argon oxygen decarburization converters, Argon-oxygen decarburizations, Bubble, Decarburization reaction, Dynamic database, Harsh environment, Liquid steels, Thermodynamic database
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-325065 (URN)10.1002/srin.202200156 (DOI)000818827800001 ()2-s2.0-85133043913 (Scopus ID)
Note

QC 20230328

Available from: 2023-03-28 Created: 2023-03-28 Last updated: 2023-11-21Bibliographically approved
Chanouian, S., Ahlin, B., Tilliander, A. & Ersson, M. (2021). Inclination Effect on Mixing Time in a Gas–Stirred Side–Blown Converter. Steel Research International, 92(10), 2100044, Article ID 2100044.
Open this publication in new window or tab >>Inclination Effect on Mixing Time in a Gas–Stirred Side–Blown Converter
2021 (English)In: Steel Research International, ISSN 1611-3683, E-ISSN 1869-344X, Vol. 92, no 10, p. 2100044-, article id 2100044Article in journal (Refereed) Published
Abstract [en]

Small-scale physical models are commonly used to investigate gas-stirred processes in steelmaking practice. The argon oxygen decarburization (AOD) converter is among various processes widely used in the metallurgy field and utilizes side blowing of oxygen and inert gas for mixing in the bath. Herein, the effect of the converter inclination on mixing time and jet-penetration length with a side-blown physical model is investigated. Scaling with the modified Froude number is applied on data from a real industrial AOD converter to achieve a system with reasonable gas flow rates. During the experiments, water is used to simulate liquid steel and air is blown through side-mounted nozzles for stirring. A NaCl tracer is added and subsequent conductivity measurements are used to measure mixing time. Overall, the penetration length is shown to be independent of inclination angle. The mixing time is found to be influenced by the change of bath height to diameter ratio, change of geometry in the bath volume, gas flow rate, and the intensified wave motion at the interface caused by the inclination of the vessel. The mixing time increase with 14% when 14° angle is applied.

Place, publisher, year, edition, pages
Wiley, 2021
Keywords
argon oxygen decarburization converter, inclinations, mixing time, penetration lengths, physical modelings, Flow of gases, Inert gases, Mixing, Oxygen, Sodium chloride, Argon oxygen decarburization converters, Conductivity measurements, Height-to-diameter ratio, Inclination angles, Jet penetration, Modified froude numbers, Penetration length, Steelmaking practice, Phase interfaces
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-310168 (URN)10.1002/srin.202100044 (DOI)000669236900001 ()2-s2.0-85109021711 (Scopus ID)
Note

QC 20220323

Available from: 2022-03-23 Created: 2022-03-23 Last updated: 2023-11-21Bibliographically approved
Chanouian, S., Pitkala, J., Larsson, H. & Ersson, M.Modelling Decarburization in the AOD Converter: A Practical CFD-Based Approach with Chemical Reactions.
Open this publication in new window or tab >>Modelling Decarburization in the AOD Converter: A Practical CFD-Based Approach with Chemical Reactions
(English)Manuscript (preprint) (Other academic)
Abstract [en]

Gas blowing technology is widely used in converter steelmaking to homogenize liquid steel and accelerate chemical reactions, with Argon oxygen decarburization (AOD) being the dominant process for stainless steelmaking. Due to the harsh environment, it is advisable to study the phenomenon using small-scale physical models and numerical simulations before conducting industrial-scale trials. This paper presents a practical computational fluid dynamics (CFD) approach for simulating the AOD process, with chemical reactions considered. This approach can simulate the entire process in a reasonable time using a standard workstation. The simulation employs a Finite Volume Method CFD approach to handle mass, momentum and energy transfer, and a local equilibrium assumption is utilized. The study shows that a practical approach can be used to model the initial stage of decarburization in the AOD process with a reduced accuracy in mass transport calculations. The accuracy of the simulation is validated using industrial data, and good agreement is found.

Keywords
AOD process, decarburization reactions, coupled model, CFD
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-339864 (URN)
Note

QC 20231122

Available from: 2023-11-21 Created: 2023-11-21 Last updated: 2023-11-22Bibliographically approved
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ORCID iD: ORCID iD iconorcid.org/0000-0001-6200-1920

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