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(English)Manuscript (preprint) (Other academic)
Abstract [en]
Charge-density waves (CDWs) in layered transition-metal dichalcogenides (TMDs) emerge from the coupled evolution of lattice vibrations and electronic states. In 2H-TaS$_2$, however, the microscopic origin of the CDW transition has remained unsettled. Here we combine inelastic X-ray scattering (IXS), angle-resolved photoemission spectroscopy (ARPES), and density-functional theory (DFT) to uncover a mechanism that deviates from the canonical soft-mode scenario. IXS reveals a momentum-localized Kohn anomaly at $q_{\mathrm{CDW}}$ that softens strongly but saturates at $\sim 4$~meV, defining a narrow precursor regime $\sim 3$~K above $T_{\mathrm{CDW}} = 77$~K. In contrast, ARPES shows a sharp electronic response at the transition: a sizeable CDW gap of $\Delta = 95 \pm 9$~meV opens abruptly below $T_{\mathrm{CDW}}$, while no pseudogap is detected above. Harmonic calculations reproduce the ordering vector but overestimate the transition scale, highlighting the importance of anharmonic fluctuations, phonon mode mixing, and electronic feedback in truncating the phonon collapse. Together, these results identify 2H-TaS$_2$ as a distinct archetype of CDW order, where an incomplete lattice softening coexists with a strong-coupling electronic gap, in sharp contrast to the complete phonon collapse recently reported in 2H-TaSe$_2$. More broadly, they demonstrate how electron–phonon coupling and lattice dynamics cooperate to generate diverse CDW pathways in TMDs.
National Category
Condensed Matter Physics
Identifiers
urn:nbn:se:kth:diva-369154 (URN)
Note
QC 20250918
2025-08-292025-08-292025-09-18Bibliographically approved