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Herting, G., Blomberg, E., Khort, A., Rogö, H., Palmi, K., Hammar, H., . . . Odnevall, I. (2026). Mechanistic insights on surface adsorption of rice-based biomolecules on stainless steel 316L and its effects on corrosion and metal migration. Journal of Food Engineering, 413, Article ID 113018.
Open this publication in new window or tab >>Mechanistic insights on surface adsorption of rice-based biomolecules on stainless steel 316L and its effects on corrosion and metal migration
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2026 (English)In: Journal of Food Engineering, ISSN 0260-8774, E-ISSN 1873-5770, Vol. 413, article id 113018Article in journal (Refereed) Published
Abstract [en]

Austenitic stainless steel (AISI 316L) is the dominant material in food processing equipment due to high corrosion resistance and mechanical durability. The shift from animal-to plant-based food processing introduces new challenges for material performance, as plant-derived biomolecules may interact differently with food-contact surfaces than animal proteins. These interactions can modify interfacial properties, with consequences for fouling, corrosion, and metal migration. Despite its importance, such effects remain scarcely studied, with only a few reports on e.g. whey and casein proteins. Knowledge on rice-derived biomolecules is particularly limited, even though rice proteins and starches are increasingly relevant in gluten-free and plant-based systems. This study examines the adsorption kinetics and interfacial properties of rice protein concentrates (RPC) and rice starch (RS) dissolved in artificial tap water (ATW) onto 316L stainless steel. In situ quartz crystal microbalance with dissipation monitoring (QCM-D) was employed to quantify adsorption dynamics, complemented by atomic force microscopy (AFM) and carbohydrate-specific opto-tracing (Carbotrace 680) to detect, and visualize adsorption patterns. Atomic absorption spectroscopy (AAS) was used to determine metal migration and evaluated with respect to European Union specific release limits (SRLs) for food-contact materials. Electrochemical measurements including open circuit potential (OCP), potentiodynamic polarization (PDP), and cyclic potentiodynamic polarization (CPDP) were employed to assess the effects of adsorption on the corrosion behavior. By demonstrating how rice-derived biomolecules interact with stainless steel and influence corrosion and metal migration, this study addresses a critical knowledge gap in the literature. The insights advance fundamental understanding of food biomolecule–metal interactions and support the design of more durable, compliant, and safe food-contact materials.

Place, publisher, year, edition, pages
Elsevier BV, 2026
Keywords
Adsorption, Corrosion, Food-contact materials, Metal migration, Rice protein, Rice starch, Stainless steel (AISI 316L)
National Category
Surface- and Corrosion Engineering Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-377323 (URN)10.1016/j.jfoodeng.2026.113018 (DOI)001690131200001 ()2-s2.0-105029728829 (Scopus ID)
Note

QC 20260227

Available from: 2026-02-27 Created: 2026-02-27 Last updated: 2026-02-27Bibliographically approved
Paschalidou, E. M., Herting, G., Chang, T., Klint, D., Leach, L., Fuertes, N., . . . Odnevall, I. (2025). Effects of different post surface treatments on the surface characteristics, corrosion resistance and metal migration from L-PBF additively manufactured 316L stainless steel. Results in Materials, 27, Article ID 100748.
Open this publication in new window or tab >>Effects of different post surface treatments on the surface characteristics, corrosion resistance and metal migration from L-PBF additively manufactured 316L stainless steel
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2025 (English)In: Results in Materials, E-ISSN 2590-048X, Vol. 27, article id 100748Article in journal (Refereed) Published
Abstract [en]

Additive manufacturing (AM) using Laser Powder Bed Fusion (L-PBF) enables the fabrication of complex metal components with high precision. However, the as-printed surfaces often exhibit high roughness, residual stresses, and partially fused particles, which can negatively impact the mechanical performance, corrosion resistance, and fatigue life. Surface treatments are therefore required to improve surface integrity, reduce defects, and enhance functional properties such as corrosion resistance. This study explores the impact of chemical and mechanical post-processing methods including pickling, clean hot isostatic pressure (HIP), Hirtization, shot peening (SP), and isotropic super finishing (C.A.S.E.) on the microstructure, surface composition and topography of L-PBF printed HIP treated 316L stainless steel surfaces in relation to their corrosion resistance and extent of metal dissolution in artificial tap water with and without chlorides (1 and 3 wt% Cl). Corrosion studies were also performed in NaCl (2.1 wt% Cl) based on the ASTM G61 standard. The utilization of a combination of electrochemical, chemical, microscopic, and spectroscopic techniques discerned notable differences for the differently surface treated AM 316L in terms of microstructure, surface topography, surface roughness, surface oxide composition and barrier properties, metal dissolution, corrosion resistance as well as pitting corrosion resistance.

Place, publisher, year, edition, pages
Elsevier BV, 2025
Keywords
316L, Electrochemical performance, L-PBF, Metal dissolution, Microstructure, Post processing, Surface composition
National Category
Manufacturing, Surface and Joining Technology Materials Chemistry Metallurgy and Metallic Materials Surface- and Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-369189 (URN)10.1016/j.rinma.2025.100748 (DOI)2-s2.0-105013100511 (Scopus ID)
Note

QC 20250829

Available from: 2025-08-29 Created: 2025-08-29 Last updated: 2025-08-29Bibliographically approved
Blomberg, E., Wang, X., Herting, G., Khort, A., Arora, A., Buxton, S., . . . Odnevall, I. (2025). Effects of sonication on particle dispersions from a size, biodissolution, cytotoxicity and transferred dose perspective – a case study on nickel and nickel oxide particles. PLOS ONE, 20(5 May), Article ID e0323368.
Open this publication in new window or tab >>Effects of sonication on particle dispersions from a size, biodissolution, cytotoxicity and transferred dose perspective – a case study on nickel and nickel oxide particles
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2025 (English)In: PLOS ONE, E-ISSN 1932-6203, Vol. 20, no 5 May, article id e0323368Article in journal (Refereed) Published
Abstract [en]

The toxicity of micro- and nanoparticles in cell culture studies is influenced by factors like particle size, agglomeration, dissolution of the particles, and methodological factors like sonication protocols. The main aim of this study was to investigate the influence of sonication on the particle size, dissolution, cytotoxicity, and dosing accuracy of nickel (Ni) metal and Ni oxide (NiO) particle dispersions. Such investigations are important to enable studies on the cellular uptake of different Ni substances in lung cells. The effect of sonication was evaluated in ultrapure water, two types of cell media, and A549 human lung cells using the tip and water bath methods. Extended sonication significantly decreased particle size and increased particle dissolution, emphasizing the need for optimized sonication conditions tailored to the specific particle type and study design. Observed findings demonstrate that the sonication step potentially can have a large impact on the results due to changes in particle characteristics, size, and dissolution, properties which are highly dependent on the particle type, solution composition, and sonication parameters. Although only small differences were observed in the limited assessment of cytotoxicity (A549 cells) in this study, further investigation is required to determine the impact of sonication on toxicity. This study also emphasizes the need to evaluate transferred dose samples due to the evident effects of agglomeration, sedimentation, and losses during sample transfer of particle dispersions. The study clearly illustrates that the choice of sonication protocol is particularly critical for toxicity studies, which are the basis of government regulatory decisions and human exposure limits.

Place, publisher, year, edition, pages
Public Library of Science (PLoS), 2025
National Category
Chemical Sciences
Identifiers
urn:nbn:se:kth:diva-363786 (URN)10.1371/journal.pone.0323368 (DOI)001488715700015 ()40344085 (PubMedID)2-s2.0-105004811146 (Scopus ID)
Note

QC 20250528

Available from: 2025-05-21 Created: 2025-05-21 Last updated: 2025-07-04Bibliographically approved
Odnevall, I. & Herting, G. (2025). Patina Formation and Aesthetic Durability of Architectural Copper and Copper Alloys in the Marine–Desert Environment of Dubai. Corrosion and Materials Degradation, 6(4), Article ID 51.
Open this publication in new window or tab >>Patina Formation and Aesthetic Durability of Architectural Copper and Copper Alloys in the Marine–Desert Environment of Dubai
2025 (English)In: Corrosion and Materials Degradation, E-ISSN 2624-5558, Vol. 6, no 4, article id 51Article in journal (Refereed) Published
Abstract [en]

The use of copper and its alloys in architecture, especially in arid regions, is growing, driven by visual appeal, functional advantages, and sustainability. Changes in visual and colorimetric appearances and patina formation were evaluated for architectural Cu metal, brass (CuZn15), bronze (CuSn4), and a golden alloy (CuZn5Al5). Coupons were exposed over 4 years in Dubai, United Arab Emirates, at a test site located 2 km from the seashore under unsheltered conditions, and at various surface inclinations. Comparative exposures were conducted in Brest, France, at sites of increasing distance from the seashore. Visual appearance was assessed by colorimetry and optical imaging; patina cross-sections were characterized by means of scanning electron microscopy and elemental analysis (SEM/EDS), and crystalline phase identification was conducted by means of x-ray diffraction (XRD). All Dubai surfaces developed red-yellowish, heterogeneous patinas with embedded sand and dust, reducing lightness and visual appeal. Inclination had minor effect, although some extent of spallation occurred on downward-facing CuSn4. Even the corrosion-resistant CuZn5Al5 alloy lost its golden hue due to the incorporation of sand and dust into the patina. In Brest, appearance depended on the distance from the seashore, with green-blue patinas near the sea and red-yellowish farther inland, similar to Dubai. Cleaning may restore some luster, but the desert exposure generally reduced the long-term aesthetic performance of all materials.

Place, publisher, year, edition, pages
MDPI AG, 2025
Keywords
aesthetic appearance, atmospheric corrosion, copper alloys, copper metal, flaking, marine–desert atmospheres, patina composition
National Category
Metallurgy and Metallic Materials
Identifiers
urn:nbn:se:kth:diva-374956 (URN)10.3390/cmd6040051 (DOI)001646219700001 ()2-s2.0-105025928588 (Scopus ID)
Note

QC 20260112

Available from: 2026-01-12 Created: 2026-01-12 Last updated: 2026-01-12Bibliographically approved
Hedberg, Y., Herting, G., Yan, K., Gichuru, J. & Odnevall, I. (2025). Reflecting on the Design and Implementation of a Corrosion Course. Corrosion, 81(8), 718-725
Open this publication in new window or tab >>Reflecting on the Design and Implementation of a Corrosion Course
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2025 (English)In: Corrosion, ISSN 0010-9312, E-ISSN 1938-159X, Vol. 81, no 8, p. 718-725Article in journal (Refereed) Published
Abstract [en]

Knowledge of corrosion (degradation of materials involving electrochemical and other chemical processes) is important for many engineering and science disciplines. Up to 875 billion dollars could be saved globally if existing corrosion knowledge had been applied. Industry and education assessors have identified corrosion education as a key area of higher education currently lacking in many engineering programs. In this paper, we present the design of a course in corrosion and surface protection given to engineering students in different materials science and chemistry Master’s programs at KTH Royal Institute of Technology, Stockholm, Sweden. We discuss the course design in terms of the students’ learning approach, concept learning, perceived usefulness of the course, psychology of predicting one’s future responsibilities for potential corrosion failures, and the need for future educational developments. We recommend including actual and real corrosion cases in corrosion classes to increase corrosion awareness, concept learning, and long-term memory of corrosion problems and concepts. Teaching a sense of responsibility for future corrosion failures is a challenging task that demands alternative and innovative approaches.

Place, publisher, year, edition, pages
Association for Materials Protection and Performance (AMPP), 2025
Keywords
concept learning, corrosion, course design, learning approach, psychology of prediction
National Category
Surface- and Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-369860 (URN)10.5006/4755 (DOI)001554020000002 ()2-s2.0-105014250439 (Scopus ID)
Note

QC 20250916

Available from: 2025-09-16 Created: 2025-09-16 Last updated: 2025-12-01Bibliographically approved
Chang, T., Leygraf, C., Herting, G., Fan, Y., Babu, P., Malkoch, M., . . . Odnevall, I. (2024). Effect of blue light illumination on atmospheric corrosion and bacterial adhesion on copper. Corrosion Science, 230, Article ID 111909.
Open this publication in new window or tab >>Effect of blue light illumination on atmospheric corrosion and bacterial adhesion on copper
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2024 (English)In: Corrosion Science, ISSN 0010-938X, E-ISSN 1879-0496, Vol. 230, article id 111909Article in journal (Refereed) Published
Abstract [en]

The effect of blue light on atmospheric corrosion of Cu and on the antimicrobial properties was explored upon exposure mimicking the condition of hygienic surface disinfection. The results show that blue light illumination enhanced the formation of Cu2O, resulting in a slightly increased corrosion resistance of Cu without pre-deposited NaCl, whereas the enhanced formation of Cu2O, CuCl and/or Cu(OH)3Cl on copper with pre-deposited NaCl caused concomitant corrosion product flaking and a reduced corrosion resistance. The blue light induced enhancement of Cu corrosion led to increased surface roughness and more pronounced integration of bacteria within the corrosion products.

Place, publisher, year, edition, pages
Elsevier BV, 2024
Keywords
Atmospheric corrosion, Bacteria (E. coli), Blue light, Chloride, Copper
National Category
Surface- and Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-343995 (URN)10.1016/j.corsci.2024.111909 (DOI)001185810700001 ()2-s2.0-85185492077 (Scopus ID)
Note

QC 20240229

Available from: 2024-02-28 Created: 2024-02-28 Last updated: 2025-02-09Bibliographically approved
Herting, G., Virolainen, E. & Odnevall, I. (2024). Patina formation and diffuse dispersion of alloying metals from weathering steels at urban atmospheric conditions—A combined laboratory and field investigation. Materials and corrosion - Werkstoffe und Korrosion, 75(10), 1282-1296
Open this publication in new window or tab >>Patina formation and diffuse dispersion of alloying metals from weathering steels at urban atmospheric conditions—A combined laboratory and field investigation
2024 (English)In: Materials and corrosion - Werkstoffe und Korrosion, ISSN 0947-5117, E-ISSN 1521-4176, Vol. 75, no 10, p. 1282-1296Article in journal (Refereed) Published
Abstract [en]

The increasing use of weathering steels (WS) has raised concerns regarding the diffuse emission of alloying elements. This research paper investigates the release of iron (Fe) and the alloying elements (Cr), copper (Cu), manganese (Mn) and nickel (Ni) from two commercially available WS at urban field conditions in Stockholm, Sweden, during 1 year and in the laboratory at simulated urban conditions. The amount of released metals is evaluated and compared with recommended levels of metals in drinking water and the formation and evolution of the protective patina is studied in parallel to assess the influence on the metal release process. Only minor amounts of the alloying elements are released and is only linked to the outermost surface composition of the patina during the very beginning of the exposure. The released amounts are found to be lower compared with the corresponding levels recommended by the World Health Organisation for drinking water.

Place, publisher, year, edition, pages
Wiley, 2024
Keywords
atmospheric corrosion, field and laboratory exposure, metal release, patina evolution, urban conditions, weathering steel
National Category
Surface- and Corrosion Engineering
Identifiers
urn:nbn:se:kth:diva-364802 (URN)10.1002/maco.202414430 (DOI)001225355500001 ()2-s2.0-85193540275 (Scopus ID)
Note

QC 20250709

Available from: 2025-06-16 Created: 2025-06-16 Last updated: 2025-07-09Bibliographically approved
Odnevall, I., Brookman-Amissah, M., Stabile, F., Ekvall, M. T., Herting, G., Vargas, M. B., . . . Rissler, J. (2023). Characterization and Toxic Potency of Airborne Particles Formed upon Waste from Electrical and Electronic Equipment Waste Recycling: A Case Study. ACS Environmental Au, 3(6), 370-382
Open this publication in new window or tab >>Characterization and Toxic Potency of Airborne Particles Formed upon Waste from Electrical and Electronic Equipment Waste Recycling: A Case Study
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2023 (English)In: ACS Environmental Au, E-ISSN 2694-2518, Vol. 3, no 6, p. 370-382Article in journal (Refereed) Published
Abstract [en]

Manual dismantling, shredding, and mechanical grinding of waste from electrical and electronic equipment (WEEE) at recycling facilities inevitably lead to the accidental formation and release of both coarse and fine particle aerosols, primarily into the ambient air. Since diffuse emissions to air of such WEEE particles are not regulated, their dispersion from the recycling plants into the adjacent environment is possible. The aim of this interdisciplinary project was to collect and characterize airborne WEEE particles smaller than 1 mu m generated at a Nordic open waste recycling facility from a particle concentration, shape, and bulk and surface composition perspective. Since dispersed airborne particles eventually may reach rivers, lakes, and possibly oceans, the aim was also to assess whether such particles may pose any adverse effects on aquatic organisms. The results show that WEEE particles only exerted a weak tendency toward cytotoxic effects on fish gill cell lines, although the exposure resulted in ROS formation that may induce adverse effects. On the contrary, the WEEE particles were toxic toward the crustacean zooplankter Daphnia magna, showing strong effects on survival of the animals in a concentration-dependent way.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2023
Keywords
electronic waste, WEEE, aerosols, environmental dispersion, characterization, ecotoxicity
National Category
Other Chemistry Topics
Identifiers
urn:nbn:se:kth:diva-340670 (URN)10.1021/acsenvironau.3c00034 (DOI)001105820700001 ()38028743 (PubMedID)2-s2.0-85178365949 (Scopus ID)
Note

QC 20231211

Available from: 2023-12-11 Created: 2023-12-11 Last updated: 2026-06-30Bibliographically approved
Ragnvaldsson, D., Herting, G., Jönsson, A. & Odnevall, I. (2022). Applying Generic Water Quality Criteria to Cu and Zn in a Dynamic Aquatic Environment-The Case of the Brackish Water Formation Strommen-Saltsjon. Water, 14(6), Article ID 847.
Open this publication in new window or tab >>Applying Generic Water Quality Criteria to Cu and Zn in a Dynamic Aquatic Environment-The Case of the Brackish Water Formation Strommen-Saltsjon
2022 (English)In: Water, E-ISSN 2073-4441, Vol. 14, no 6, article id 847Article in journal (Refereed) Published
Abstract [en]

The EU Water Framework Directive stipulates that all EU waterways shall have good chemical and ecological status by 2027. Methodologies are described for how to assess and classify waterbodies and make 7-year management plans. Aquatic risk assessment methodologies and environmental quality standards are defined and a biotic ligand model methodology is available to assess the influence of water chemistry on the ability of aquatic organisms to take up metals. Aquatic status classification practices of naturally occurring river basin-specific metals are discussed, specifically how Cu and Zn water quality criteria guideline values have been adopted and defined for Swedish coastal and estuarine waters and how well they represent possible ecological risks. Calculations of bioavailability and ecotoxicity are conducted using recognised models for the Strommen-Saltsjon water body in Stockholm, in which naturally occurring metals, especially Cu, have among the highest background concentrations of Sweden. Proposals are made to improve risk assessment methodologies to better reflect the vitality of living organisms, and to what extent current levels of these metals in Swedish waterways may influence their welfare. The study concludes that a more local assessment including, e.g., studies of the benthic fauna would be relevant for ecological status classification.

Place, publisher, year, edition, pages
MDPI AG, 2022
Keywords
water quality criteria guideline values, status classification, brackish water, copper, zinc
National Category
Environmental Sciences
Identifiers
urn:nbn:se:kth:diva-310778 (URN)10.3390/w14060847 (DOI)000774510000001 ()2-s2.0-85126345141 (Scopus ID)
Note

QC 20220530

Available from: 2022-04-07 Created: 2022-04-07 Last updated: 2023-08-28Bibliographically approved
Zhang, S.-T. -., Maltseva, A., Herting, G., Guillemoles, J.-F. -., Schneider, N., Odnevall, I. & Volovitch, P. (2022). Importance of atmospheric aerosol pollutants on the degradation of Al2O3 encapsulated Al-doped zinc oxide window layers in solar cells. Progress in Photovoltaics, 30(5), 552-566
Open this publication in new window or tab >>Importance of atmospheric aerosol pollutants on the degradation of Al2O3 encapsulated Al-doped zinc oxide window layers in solar cells
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2022 (English)In: Progress in Photovoltaics, ISSN 1062-7995, E-ISSN 1099-159X, Vol. 30, no 5, p. 552-566Article in journal (Refereed) Published
Abstract [en]

Atmospheric aerosol pollutants are considered for the first time for the durability evaluation of non-metallic photovoltaic materials on the example of pristine and Al2O3-encapsulated Al-doped zinc oxide (AZO) window layers. The AZO samples were exposed to a varied temperature and humidity cycle, completed or not by a daily deposition of (NH4)2SO4 or NaCl aerosols, typical pollutants in rural and marine environments, respectively. The samples exposed with and without the pollutants were compared after 1 and 2 weeks of the test. Optical transmittance and conductivity significantly degraded only for the samples exposed with the pollutants. Raman spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy evidenced localized dissolution of the AZO film and chemical modification of the Al2O3 encapsulation. The most severe degradation was caused by (NH4)2SO4, which was attributed to the high stability of soluble [Zn (NH3)42+] complexes. The Al2O3 encapsulation improved chemical and physical stability of AZO in the presence of (NH4)2SO4 but not in the presence of NaCl. The latter can be explained by pitting corrosion of Al2O3. Optical transmission curves are coherent with the AZO layer thinning in the presence of NaCl and very localized AZO dissolution (most likely grain boundary etching) in the presence of (NH4)2SO4. The enhanced degradation of encapsulated AZO in the presence of atmospheric aerosol pollutants suggests that they cannot be neglected in the evaluation of barrier protection capacities of novel encapsulates and, more generally, in the outdoor durability assessment of novel photovoltaic materials and devices. 

Place, publisher, year, edition, pages
Wiley, 2022
Keywords
Al:ZnO transparent conductive oxide, Al2O3-encapsulation, atmospheric pollutants, flexible photovoltaics, outdoor durability, Alumina, Aluminum oxide, Atmospheric chemistry, Atmospheric corrosion, Atmospheric humidity, Atmospheric thermodynamics, Chemical modification, Chemical stability, Dissolution, Etching, Grain boundaries, II-VI semiconductors, Light transmission, Seawater corrosion, Sodium chloride, X ray photoelectron spectroscopy, Zinc oxide, Aerosol pollutants, Al-doped zinc oxide, Durability evaluation, Localised, Non-metallic, Oxide samples, Photovoltaic materials, Photovoltaics, Research and application, Window layer, Atmospheric aerosols
National Category
Human Geography Radiology, Nuclear Medicine and Medical Imaging Atom and Molecular Physics and Optics
Identifiers
urn:nbn:se:kth:diva-317505 (URN)10.1002/pip.3527 (DOI)000734618500001 ()2-s2.0-85121716308 (Scopus ID)
Note

QC 20220919

Available from: 2022-09-19 Created: 2022-09-19 Last updated: 2022-09-19Bibliographically approved
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ORCID iD: ORCID iD iconorcid.org/0000-0002-2123-2201

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