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2020 (English)In: Metals, ISSN 2075-4701, Vol. 10, no 9, article id 1243Article in journal (Refereed) Published
Abstract [en]
The findings in this work enhance the understanding of oxidation mechanisms and scale growth at high temperatures of a high strength low alloy (HSLA) steel for improving surface quality during continuous casting. The oxidation phenomenon was investigated under dry air and water vapor atmospheres by heating specimens at 1000, 1100, and 1200 degrees C at different holding times. Temperature and time had great effects on the kinetics, where faster (i.e., parabolic) oxidation rates were present under water vapor when compared with the dry air condition. Temperature strongly influenced the number of defects, such as pores, voids, gaps and micro-cracks, formed in the oxide scale. A phase analysis confirmed the presence of FeO as the first phase formed at the steel surface, Fe(3)O(4)as the middle and thicker phase, and Fe(2)O(3)as the last phase formed in the oxide/air interface. The micromechanics of the oxides demonstrated that a combination of phases with high (wustite) and low plasticity (magnetite and hematite) could also have been the reason for the uneven cooling during Continuous Casting (CC) that resulted in the undesired surface quality of the steel slabs. This work gives a good look at the oxide scale effect on the surface quality of steel slabs through an understanding the kinetics during oxidation.
Place, publisher, year, edition, pages
MDPI, 2020
Keywords
oxide scale, water vapor, kinetics, continuous casting, HSLA steel
National Category
Materials Engineering
Identifiers
urn:nbn:se:kth:diva-285650 (URN)10.3390/met10091243 (DOI)000580859600001 ()2-s2.0-85090899503 (Scopus ID)
Note
QC 20201110
2020-11-102020-11-102022-06-25Bibliographically approved