Nonlinear resonant Auger spectroscopy in CO using an x-ray pump-control scheme
2016 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 94, no 6, article id 06413Article in journal (Refereed) Published
Abstract [en]
In the present paper we propose nonlinear femtosecond x-ray pump-probe spectroscopy to study the vibrational dynamics of a core-excited molecular state and discuss numerical results in CO. A femtosecond pump resonantly excites the carbon core-excited 1s-1π∗ state of the CO molecule. A second strong probe (control) pulse is applied at variable delay and is resonantly coupled to a valence excited state of the molecule. The strong nonlinear coupling of the control pulse induces Rabi flopping between the two electronic states. During this process, a vibrational wave packet in the core-excited state is created, which can be effectively manipulated by changing the time delay between pump and control pulses. We present an analysis of the resonant Auger electron spectrum and the transient absorption or emission spectrum on the pump transition and discuss their information content for reconstruction of the vibrational wave packet.
Place, publisher, year, edition, pages
American Physical Society , 2016. Vol. 94, no 6, article id 06413
Keywords [en]
Absorption spectroscopy, Augers, Carbon, Delay control systems, Emission spectroscopy, Excited states, Molecules, Optical pumping, Probes, Time delay, Wave packets, Core-excited state, Information contents, Resonant Auger spectroscopy, Strong nonlinear coupling, Transient absorption, Vibrational dynamics, Vibrational wave packets, X ray pump-probe spectroscopy
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:kth:diva-199701DOI: 10.1103/PhysRevA.94.063413ISI: 000390213700009Scopus ID: 2-s2.0-85006066520OAI: oai:DiVA.org:kth-199701DiVA, id: diva2:1065187
Funder
Knut and Alice Wallenberg Foundation, KAW-2013.0020Swedish Research Council
Note
QC 20170106
2017-01-132017-01-132024-03-18Bibliographically approved