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Femtosecond-resolved imaging of a single-particle phase transition in energy-filtered ultrafast electron microscopy
Ulsan Natl Inst Sci & Technol UNIST, Coll Nat Sci, Dept Chem, 50 UNIST gil, Ulsan 44919, South Korea.;Inst Basic Sci, Ctr Soft & Living Matter, 50 UNIST gil, Ulsan 44919, South Korea.;CALTECH, Div Chem & Chem Engn, Pasadena, CA 91125 USA..ORCID iD: 0000-0002-8690-8313
Ulsan Natl Inst Sci & Technol UNIST, Coll Nat Sci, Dept Chem, 50 UNIST gil, Ulsan 44919, South Korea.;Inst Basic Sci, Ctr Soft & Living Matter, 50 UNIST gil, Ulsan 44919, South Korea..
KTH, School of Engineering Sciences (SCI), Applied Physics, Materials and Nanophysics.
UNIST, Sch Energy & Chem Engn, 50 UNIST gil, Ulsan 44919, South Korea..
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2023 (English)In: Science Advances, E-ISSN 2375-2548, Vol. 9, no 4, article id add5375Article in journal (Refereed) Published
Abstract [en]

Using an energy filter in transmission electron microscopy has enabled elemental mapping at the atomic scale and improved the precision of structural determination by gating inelastic and elastic imaging electrons, respec-tively. Here, we use an energy filter in ultrafast electron microscopy to enhance the temporal resolution toward the domain of atomic motion. Visualizing transient structures with femtosecond temporal precision was achieved by selecting imaging electrons in a narrow energy distribution from dense chirped photoelectron packets with broad longitudinal momentum distributions and thus typically exhibiting picosecond durations. In this study, the heterogeneous ultrafast phase transitions of vanadium dioxide (VO2) nanoparticles, a repre-sentative strongly correlated system, were filmed and attributed to the emergence of a transient, low-symmetry metallic phase caused by different local strains. Our approach enables electron microscopy to access the time scale of elementary nuclear motion to visualize the onset of the structural dynamics of matter at the nanoscale.

Place, publisher, year, edition, pages
American Association for the Advancement of Science (AAAS) , 2023. Vol. 9, no 4, article id add5375
National Category
Condensed Matter Physics
Identifiers
URN: urn:nbn:se:kth:diva-325084DOI: 10.1126/sciadv.add5375ISI: 000934904500022PubMedID: 36706188Scopus ID: 2-s2.0-85147091059OAI: oai:DiVA.org:kth-325084DiVA, id: diva2:1746751
Note

QC 20230329

Available from: 2023-03-29 Created: 2023-03-29 Last updated: 2023-03-29Bibliographically approved

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Ji, ShaozhengWeissenrieder, Jonas

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