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Patina formation and diffuse dispersion of alloying metals from weathering steels at urban atmospheric conditions—A combined laboratory and field investigation
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0002-2123-2201
SSAB, Raahe, Finland.
KTH, School of Engineering Sciences in Chemistry, Biotechnology and Health (CBH), Chemistry, Surface and Corrosion Science.ORCID iD: 0000-0003-2206-0082
2024 (English)In: Materials and corrosion - Werkstoffe und Korrosion, ISSN 0947-5117, E-ISSN 1521-4176, Vol. 75, no 10, p. 1282-1296Article in journal (Refereed) Published
Abstract [en]

The increasing use of weathering steels (WS) has raised concerns regarding the diffuse emission of alloying elements. This research paper investigates the release of iron (Fe) and the alloying elements (Cr), copper (Cu), manganese (Mn) and nickel (Ni) from two commercially available WS at urban field conditions in Stockholm, Sweden, during 1 year and in the laboratory at simulated urban conditions. The amount of released metals is evaluated and compared with recommended levels of metals in drinking water and the formation and evolution of the protective patina is studied in parallel to assess the influence on the metal release process. Only minor amounts of the alloying elements are released and is only linked to the outermost surface composition of the patina during the very beginning of the exposure. The released amounts are found to be lower compared with the corresponding levels recommended by the World Health Organisation for drinking water.

Place, publisher, year, edition, pages
Wiley , 2024. Vol. 75, no 10, p. 1282-1296
Keywords [en]
atmospheric corrosion, field and laboratory exposure, metal release, patina evolution, urban conditions, weathering steel
National Category
Surface- and Corrosion Engineering
Identifiers
URN: urn:nbn:se:kth:diva-364802DOI: 10.1002/maco.202414430ISI: 001225355500001Scopus ID: 2-s2.0-85193540275OAI: oai:DiVA.org:kth-364802DiVA, id: diva2:1970171
Note

QC 20250709

Available from: 2025-06-16 Created: 2025-06-16 Last updated: 2025-07-09Bibliographically approved

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Herting, GunillaOdnevall, Inger

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